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Li-ion batteries (LIBs) now have made inroads into the electric vehicle market with high energy densities, yet they still suffer from slow kinetics limited by the graphite anode. Here, we design electrolytes enabling extreme fast charging (XFC) of microsized graphite anode without Li plating. The comprehensive characterizations and simulations on the diffusion of Li+ in the bulk electrolyte, charge-transfer process, and the solid electrolyte interphase (SEI) demonstrate that high ionic conductivity, low desolvation energy of Li+ and protective SEI are essential for XFC. Based on the criterion, two fast-charging electrolytes are designed. Low-voltage 1.8 M LiFSI in 1,3-Dioxolane (DOL) ether electrolyte is for LiFePO4||graphite cells, while high-voltage 1.0 M LiPF6 in a mixture of 4-Fluoroethylene Carbonate (FEC) and Acetonitrile (AN) (7:3 by vol.) is for LiNi0.8Co0.1Mn0.1O2||graphite cells. The former electrolyte enables the graphite electrode to achieve 180 mAh g−1 at 50C (1C=370 mAh g-1), which is 10 times higher than that with conventional electrolyte. The latter electrolyte enables LiNi0.8Co0.1Mn0.1O2||graphite cells (2 mAh cm−2, N/P ratio = 1) to provide a record-breaking reversible capacity of 170 mAh g-1 at 4C charge and 0.3C discharge. This work unveils the key mechanisms for XFC and provides instructive electrolyte design principles for practical fast-charging LIBs with graphite anodes.

A method to deposit NiOx thin films by employing combustion reactions is reported and a low processing temperature of 175 °C is demonstrated. The resulting NiOx films exhibit high work functions, excellent optical transparency, and flat surface features. The NiOx thin films are employed as hole‐transport interlayers in organic solar cells and polymer light‐emitting diodes, exhibiting superior electrical properties.

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