Water-soluble red afterglow imaging agents based on ecofriendly nanomaterials have potential application in timegated afterglow bioimaging due to their larger penetration depth and nondurable excitation. Herein, red afterglow imaging agents consisted of Rhodamine B (RhB) and carbon nanodots (CNDs) have been designed and demonstrated. In these agents, CNDs act as energy donors, and RhB acts as an energy acceptor. Both of them are confined into a hydrophilic silica shell to form a CNDs-RhB@silica nanocomposite. The phosphorescence emission spectrum of the CNDs and the absorption spectrum of the RhB match well, and efficient energy transfer from the CNDs to the RhB via Forster resonant energy transfer process can be achieved, with a transfer efficiency can reach 99.2%. Thus, the as-prepared nanocomposite can emit a red afterglow in aqueous solution, and the afterglow spectrum of CNDs-RhB@silica nanocomposite can extend to the first near-infrared window (NIR-I). The luminescence lifetime and afterglow quantum yield (QY) of the CNDs-RhB@silica can reach 0.91 s and 3.56%, respectively, which are the best results in red afterglow region. Time-gated in vivo afterglow imaging has been demonstrated by using the CNDs-RhB@silica as afterglow agents.
This paper presents an investigation of the use of a volume-choke-volume low-pass filter to achieve gas pulsation attenuation in a reciprocating compressor piping system, with a focus on its frequency response characteristics and influence on the actual attenuation effects. A three-dimensional acoustic model of the gas pulsation was established for a compressor discharge piping system with and without the volume-choke-volume filter, based on which the gas column natural frequencies of the piping system and the pressure wave profiles were predicted by means of the finite element method. The model was validated by comparing the predicted results with the experimental data. The results showed that the characteristic frequency of the filter was sensitive to both diameter and length of the choke but independent of the parameters of the piping beyond the filter. It is worth noting that the characteristic frequency of the filter constituted one order of the gas column natural frequencies of the piping system with the filter. The pressure pulsation levels in the piping system downstream of the filter could be significantly attenuated especially for the pulsation components at frequencies above the filter’s characteristic frequency. The measured peak-to-peak pressure pulsation at the outlet of the filter was approximately 61.7% lower than that of the surge bottle with the same volume.
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