Aerogel with low
density, high porosity, and large surface area
is a promising structure for the next generation of high-performance
thermal insulation fibers and textiles. However, aerogel fibers suffer
from weak mechanical properties or complex fabricating processes.
Herein, a facile wet-spinning approach for fabricating nanofibrous
Kevlar (KNF) aerogel threads (i.e., aerogel fibers)
with high thermal insulation under extreme environments is demonstrated.
The aerogel fibers made from nanofibrous Kevlar render a high specific
surface area (240 m2/g) and wide-temperature thermal stability.
The flexible and strong KNF aerogel fibers are woven into textiles
to illustrate the excellent thermal insulation property under extreme
temperature (−196 or +300 °C) and at room temperature.
COMSOL simulation is applied to calculate the thermal conductivity
of a single aerogel fiber and find an effective way to improve the
thermal insulation property of the aerogel fiber. Furthermore, a series
of functionalized fibers or textiles based on KNF aerogel fibers,
such as phase-change fibers, conductive fibers, and hydrophobic textiles,
have been prepared. Such KNF aerogel fibers represent a promising
direction for the next generation of high-performance fibrous thermal-insulation
materials.
Wire-, ribbon-, and sphere-like nanostructures of polypyrrole have been synthesized by solution chemistry methods in the presence of various surfactants (anionic, cationic, or nonionic surfactant) with various oxidizing agents [ammonium persulfate (APS) or ferric chloride (FeCl3), respectively]. The surfactants and oxidizing agents used in this study have played a key role in tailoring the nanostructures of polypyrrole during the polymerization. It is inferred that the lamellar structures of a mesophase are formed by self-assembly between the cations of a long chain cationic surfactant [cetyltrimethylammonium bromide (CTAB) or dodeyltrimethylammonium bromide (DTAB)] and anions of oxidizing agent APS. These layered mesostructures are presumed to act as templates for the formation of wire- and ribbon-like polypyrrole nanostructures. In contrast, if a short chain cationic surfactant octyltrimethylammonium bromide (OTAB) or nonionic surfactant poly(ethylene glycol) mono-p-nonylphenyl ether (Opi-10) is used, sphere-like polypyrrole nanostructures are obtained, whichever of the oxidizing agents mentioned above is used. In this case, micelles resulting from self-assembly among surfactant molecules are envisaged to serve as the templates while the polymerization happens. It is also noted that, if anionic surfactant sodium dodeyl surfate (SDS) is used, no characteristic nanostructures of polypyrrole were observed. This may be attributed to the doping effect of anionic surfactants into the resulting polypyrrole chains, and as a result, micelles self-assembled among surfactant molecules are broken down during the polymerization. The effects of monomer concentration, surfactant concentration, and surfactant chain length on the morphologies of the resulting polypyrrole have been investigated in detail. The molecular structures, composition, and electrical properties of the nanostructured polypyrrole have also been investigated in this study.
Wearable devices and systems demand multifunctional units with intelligent and integrative functions. Smart fibers with response to external stimuli, such as electrical, thermal, and photonic signals, etc., as well as offering energy storage/conversion are essential units for wearable electronics, but still remain great challenges. Herein, flexible, strong, and self-cleaning graphene-aerogel composite fibers, with tunable functions of thermal conversion and storage under multistimuli, are fabricated. The fibers made from porous graphene aerogel/organic phase-change materials coated with hydrophobic fluorocarbon resin render a wide range of phase transition temperature and enthalpy (0-186 J g ). The strong and compliant fibers are twisted into yarn and woven into fabrics, showing a self-clean superhydrophobic surface and excellent multiple responsive properties to external stimuli (electron/photon/thermal) together with reversible energy storage and conversion. Such aerogel-directed smart fibers promise for broad applications in the next-generation of wearable systems.
Infrared (IR) stealth is essential
not only in high technology
and modern military but also in fundamental material science. However,
effectively hiding targets and rendering them invisible to thermal
infrared detectors have been great challenges in past decades. Herein,
flexible, foldable, and robust Kevlar nanofiber aerogel (KNA) films
with high porosity and specific surface area were fabricated first.
The KNA films display excellent thermal insulation performance and
can be employed to incorporate with phase-change materials (PCMs),
such as polyethylene glycol, to fabricate KNA/PCM composite films.
The KNA/PCM films with high thermal management capability and infrared
emissivity comparable to that of various backgrounds demonstrate high
performance in IR stealth in outdoor environments with solar illumination
variations. To further realize hiding hot targets from IR detection,
combined structures constituted of thermal insulation layers (KNA
films) and ultralow IR transmittance layers (KNA/PCM) are proposed.
A hot target covered with this combined structure becomes completely
invisible in infrared images. Such KNA/PCM films and KNA–KNA/PCM
combined structures hold great promise for broad applications in infrared
thermal stealth.
Lightweight, robust, and thin aerogel films with multifunctionality are highly desirable to meet the technological demands of current society. However, fabrication and application of these multifunctional aerogel films are still significantly underdeveloped. Herein, we demonstrate a multifunctional aerogel film composed of strong aramid nanofibers (ANFs), conductive carbon nanotubes (CNTs), and hydrophobic fluorocarbon (FC) resin. The obtained hybrid aerogel film exhibits large specific surface area (232.8 m 2 •g −1 ), high electrical conductivity (230 S•m −1 ), and excellent hydrophobicity (contact angle of up to 137.0°) with exceptional Joule heating performance and supreme electromagnetic interference (EMI) shielding efficiency. The FC coating renders the hydrophilic ANF/CNT aerogel films hydrophobic, resulting in an excellent self-cleaning performance. The high electrical conductivity enables a low-voltage-driven Joule heating property and an EMI shielding effectiveness (SE) of 54.4 dB in the X-band at a thickness of 568 μm. The specific EMI SE is up to 33528.3 dB•cm 2 •g −1 , which is among the highest values of typical metal-, conducting-polymer-, or carbon-based composites. This multifunctional aerogel film holds great promise for smart garments, electromagnetic wave shielding, and personal thermal management systems.
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