Ti6Al4V artificial implants are increasingly demanded for addressing human dysfunction caused by an aging population and major diseases. However, they are restricted due to the release of vanadium and aluminum ions in the process of corrosion and wear. This work is aimed to provide a protective film for Ti6Al4V artificial implants, and then, a Si-incorporated diamond-like carbon (Si-DLC) film and Si-and N-incorporated DLC (SiN-DLC) film were deposited on the surface of Ti6Al4V by plasma-enhanced chemical vapor deposition. Results suggest that the thickness of the as-deposited DLC film is approximately 2 μm, and the SiN-DLC film shows the lowest surface roughness (53.0 ± 3.6 nm) compared with the Ti6Al4V and DLC films. The above DLC film possesses high mechanical properties compared with Ti6Al4V, and the SiN-DLC film shows the best resistance to plastic deformation. In addition, the DLC film exhibits high adhesive strength (>13 N) with Ti6Al4V, which is a prerequisite for service in liquid environments. Whether in SBF solution or SBF + BSA solution, the friction coefficient and wear rate of the above DLC film are much lower than those of Ti6Al4V, and the SiN-DLC film displays the optimal tribological properties (0.072 and 1.82 × 10 −7 mm 3 •N −1 •m −1 , respectively). Moreover, Si-DLC and SiN-DLC films possess similar corrosion resistance but are far better than Ti6Al4V. Cytotoxicity test results show that the SiN-DLC film can significantly improve cell viability and promote cell proliferation to a certain extent. Consequently, the SiN-DLC film is a protective film with more potential for artificial implants.
Abstract. The vertical distribution of dust aerosol and its radiative properties are analysed using the data measured by the micropulse lidar, profiling microwave radiometer, sunphotometer, particulate monitor, and nephelometer at the Semi-Arid Climate and Environment Observatory of Lanzhou University (SACOL) during a dust storm from 27 March to 29 March 2007. The analysis shows that the dust aerosol mainly exists below 2 km in height, and the dust aerosol extinction coefficient decreases with height. The temporal evolution of aerosol optical depth (AOD) during the dust storm is characterized by a sub-maximum at 22:00 (Beijing Time), 27 March and a maximum at 12:00, 28 March. The AOD respectively derived by lidar and sunphotometer shows a good consistency. The PM 10 concentration and aerosol scattering coefficient share similar variation trends, and their maximums both appear at 22:00, 27 March.The aerosol extinction coefficient and relative humidity have the similar trends and their maximums almost appear at the same heights, which presents a correlation between extinction coefficient and relative humidity known as aerosol hygroscopicity. The relative humidity is related with temperature, and then the temperature will affect the aerosol extinction properties by modifying the relative humidity condition.The aerosol extinction coefficient, scattering coefficient, and PM 10 concentration present good linear correlations. The correlation coefficients of the aerosol scattering coefficients of 450, 520, and 700 nm and PM 10 concentration, of aerosol extinction coefficient retrieved by lidar at 532 nm and PM 10 concentration, and of aerosol extinction and scattering coefficient are respectively 0.98, 0.94, and 0.96.
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