The effect of CeO2 content on the microstructure and properties of SiCp/Al-Si composites prepared by powder metallurgy was studied, and the mechanism of CeO2 in composites was deeply analyzed. The results show that the addition of the appropriate amount of CeO2 can refine the Si particles and improve the tensile properties of the SiCp/Al-Si composites. As the CeO2 content increases from 0 to 0.4 vol%, the particle size of the Si phase shows a tendency to decrease first and then increase, while the tensile strength, yield strength, and elongation of the composites show a trend of first increasing and then decreasing. When the CeO2 content is 0.2 vol%, the refining effect of CeO2 and the tensile properties of composites are the best. The fracture mode of SiCp/Al-Si composites with a rare earth addition is a mixed fracture. There are three main mechanisms for CeO2 in SiCp/Al-Si composites. One is when CeO2 serves as the nucleation substrate of Si phase to refine Si particles. The second is when CeO2 reacts with the alloying elements in the aluminum matrix to form a new phase, CeCu2Si2, which can not only play a role of dispersion strengthening, but also improve the bonding strength between Al matrix and Si particles. The third is the pinning effect of CeO2 and CeCu2Si2 particles on grain boundaries or phase boundaries to refine aluminum grains.
This paper takes nano-SiCp/Al–7Si matrix composites prepared by powder metallurgy as the research object. With the help of advanced microstructure characterization techniques and performance analysis methods, the effect of nano-SiCp volume fraction on the microstructure and properties of composites is systematically studied. Based on optimizing the volume fraction of nano-SiCp, the thermal deformation behavior of the composites is investigated. It was found that with an increase of nano-SiCp content, the distribution uniformity of nano-SiCp decreases gradually. And because the surface of nano-SiCp is easy to adsorb gas and the aggregated distribution of nano-SiCp is not conducive to the sintering process, the density of the composites shows a gradually decreasing trend. The hardness of the composites tends increasing gradually, and the increase in amplitude gradually decreases. Due to the addition of nano-SiCp, there are many interfaces between SiCp and Al matrix, and cracks are prone to initiation and expansion at the interface. Therefore, as the volume fraction of nano-SiCp increases, the elongation of nano-SiCp/Al–7Si composites gradually decreases. When the volume fraction of nano-SiCp is 2%, the strength of the composites reaches the maximum value of 217 MPa. Compared with the Al–Si alloy without adding nano-SiCp, the results increased by 37.3%. In addition, with the decrease of strain rate and the increase of deformation temperature, the dislocation density in the composites gradually decreases, and the dynamic softening progresses more fully. The dynamic recrystallization nucleation mechanism mainly includes the subcrystal merging mechanism and the grain boundary bowing mechanism.
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