A new high-performance surface-enhanced Raman scattering (SERS) substrate with extremely high SERS activity was produced. This SERS substrate combines the advantages of Au film over nanosphere (AuFON) substrate and Ag nanoparticles (AgNPs). A three order enhancement of SERS was observed when Rhodamine 6G (R6G) was used as a probe molecule to compare the SERS effects of the new substrate and commonly used AuFON substrate. These new SERS substrates can detect R6G down to 1 nM. The new substrate was also utilized to detect melamine, and the limit of detection (LOD) is 1 ppb. A linear relationship was also observed between the SERS intensity at Raman peak 682 cm−1 and the logarithm of melamine concentrations ranging from 10 ppm to 1 ppb. This ultrasensitive SERS substrate is a promising tool for detecting trace chemical molecules because of its simple and effective fabrication procedure, high sensitivity and high reproducibility of the SERS effect.
The zero bias stability, which is an important performance parameter for vibratory cylinder gyroscopes, is high sensitive to temperature change. It is considered that the varying temperature makes the vibration mode axes unstable, which has significant influence on the zero bias stability. This paper will investigate this problem in detail. First, the relationships between the angular positions of vibration mode axes and the zero bias are analyzed. Secondly, the thermal-modal model of the cylinder resonator with several defects such as mass imbalance, frequency split (FS), and geometry errors are developed by ANSYS. Simulation results show that with the increase of temperature, angular positions of the vibration mode axes obviously change, which leads to a dramatic zero bias drift. Finally, several major influence factors on the angular position stability of vibration mode axes, including frequency split, geometry errors, thermal elastic modulus coefficient (TEMC) and thermal expansion coefficient (TEC) are analyzed in detail. Simulation results in this paper will be helpful for deep understanding of the drift principle of zero bias induced by temperature for vibratory cylinder gyroscopes and also be helpful for further temperature compensation or control.
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