A new isomalabaricane triterpenoid, stellettin A [1], was isolated from the sponge Stelletta tenuis collected off Hainan Island, People's Republic of China. Its structure and stereochemistry were established by analysis of its spectral data and reference to related compounds.
Nowadays, physical absorption has become a feasible method offering an efficient and green route to remove organic pollutants from the industrial wastewater. Inspired by polydopamine (PDA) chemistry, one-dimensional PDA-functionalized multiwalled carbon nanotubes (MWCNT-PDA) were creatively introduced into graphene aerogel framework to synthesize a robust graphene/MWCNT-PDA composite aerogel (GCPCA). The whole forming process needed no additional reducing agents, significantly reducing the contamination emissions to the environment. The GCPCA exhibited outstanding repeatable compressibility, ultralight weight, as well as hydrophobic nature, which were crucial for highly efficient organic pollution absorption. The MWCNTs in moderate amounts can provide the composite aerogels with desirable structure stability and extra specific surface area. Meanwhile, the eventual absorption performance of GCPCAs can be improved by optimizing the microporous structure. In particular, a novel "cabbagelike" hierarchical porous structure was obtained as the prefreezing temperature was decreased to -80 °C. The miniaturization of pore size around the periphery of GCPCA enhanced the capillary flow in aerogel channels, and the super-absorption capacity for organic solvents was up to 501 times (chloroform) its own mass. Besides, the GCPCAs exhibited excellent reusable performance in absorption-squeezing, absorption-combustion, and absorption-distillation cycles according to the characteristic of different organic solvents. Because of the viable synthesis method, the resulting GCPCAs with unique performance possess broad and important application prospects, such as oil pollution cleanup and treatment of chemical industrial wastewater.
With excellent strength and ductility properties, transformation induced plasticity (TRIP) steels are superior to ordinary commercial steels and have great application potential in the automobile industry. However, the continuous casting of TRIP steels is associated with challenges owing to its high aluminium content, approximately 0?5-1?8%. The reaction of aluminium near the steel/slag interface continuously changes the basicity of conventional lime-silica based mould fluxes causing variation in the flux physical properties between the solidifying shell and mould wall. Therefore, the heat transfer process is unstable and the surface quality of the as-cast slab is not guaranteed.To reduce the reactivity of aluminium in TRIP steel during casting, it is suggested to replace the lime-silica based fluxes with a lime-alumina based mould flux, based on laboratory measurements and industrial trials. The trials showed great improvement in the slab surface quality and no depression defect was noticed so far.
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