Phosphorus (P) is one of the nutrients that most limits agricultural productivity, especially in tropical soils. Enriched biochar has been proposed to increase the bioavailability of P and other nutrients in the soil. Thus, the objective of this study was to evaluate the availability of P in phosphate biochar (composed of biomass and soil) as a function of the triple superphosphate mixture before and after the pyrolysis process. We produced eight types of enriched biochar via pyrolysis by combining sandy or clayey soil with rice or coffee husk, and by adding triple superphosphate before or after pyrolysis. The heating of the phosphate fertilizer during the pyrolysis process resulted in a higher crystallinity of the phosphates, lower content of labile fractions of P and lower content of available P in phosphate biochars than when the superphosphate was added after pyrolysis.

Coastal lagoons are habitats of great environmental value. However, they are currently subject to major threats, particularly due to increasing sea levels. This study aims to identify changes—both natural and induced by anthropic activity—and their impact on the recent evolution of three different types of coastal lagoons in Galicia (Louro, Vixán, and Xuño). The application of information obtained through laser imaging detection and ranging (LiDAR) techniques suggests that the outer limits of the three lagoon systems have not experienced any relevant changes in the last 60 years (i.e., no occupation of the lagoon area has been identified). However, the internal configuration of these wetland areas has experienced some alterations. A generalized increase in the area occupied by macrophytic communities (Phragmites australis, Scirpus maritimus, Juncus maritimus, etc.) has been observed. Image interpretation by geographic information systems (GIS) and field surveys suggest that the area currently occupied by macrophytes experienced a 7% to 63% increase at the expense of the free water body. This loss of flooded area is consistent with the increase in sedimentation rates associated with the convergence of several causes, such as the abandonment of traditional macrophyte biomass harvesting and agricultural activities around the lagoons, the expansion of riparian forests, and sediment contributions by erosion due to recurrent forest fires within the drainage basins of each lagoon. Finally, water and sediment composition suggest that, of the three studied lagoons, two of them (Louro and Vixán) are included within the definition of “coastal lagoons” (habitat code 1150) by the Habitats Directive (Directive 92/43/EEC), while the Xuño lagoon should be considered a “natural eutrophic lake” (habitat code 3150).

Sedimentary coastal areas change rapidly and are economically and environmentally important. This research focuses on determining the extent to which natural dynamics and human activity have contributed to visible changes on Rodas, Cíes Islands in southwestern Galicia (NW Spain). The number of visitors to the islands has increased in recent years, and the port infrastructure has therefore been expanded. Previously, this zone experimented with important sand extraction phases. These changes have influenced the ecosystem directly by modifying the sedimentary behavior and indirectly by promoting even greater numbers of visitors to the area. Aerial images and orthophotographs of the study zone were examined to identify changes that have taken place over the last sixty-one years (1956–2017). Changes in the position of the shoreline, defined as the boundary of the dune vegetation, were mapped at different times between 1956 and 2017. Changes in the shoreline were quantified using GIS (Geographic Information System) technology and Digital Shoreline Analysis System (DSAS) software. The findings revealed that the system regressed by more than 30 m between 1956 and 1981, in part as a result of sand extraction. We also identified different erosion/accretion phases that occurred before the reformation of the Rodas dock in 2010. The system is currently undergoing important changes, especially in the northern area, with a regression of 14.14 m in the last seven years. In this context, LiDAR analysis from 2010 and 2015 using Geomorphic Change Detection (GCD) tools allowed variations in the dune system to be verified. The elevation in the study zone increased in 83% of the area, mainly in the frontal dune and close to the winter inlet (north sector). However, the variations were very small.

The research and application of biochars enriched with minerals have increased in recent years; however, the mineral fraction used consists of specific minerals, such as clay minerals and synthesized compounds. In this work, the effects of adding two specific soil types (sandy and clayey) to rice and coffee husks in order to generate biochars via pyrolysis was investigated. Chemical, physical–chemical, thermal, spectroscopic and crystallographic analyses were conducted on the produced biochars. The study confirmed that the presence of mineral soils during the pyrolysis process increases the yield, C retention ratio, and specific surface area. It also decreases the pH, cation exchange capacity (CEC), nutrient content, and carbon-to-nitrogen ratio of biochars. However, the biochars produced by mixing coffee husks and mineral soils still demonstrate a capacity to increase the pH and the CEC of tropical soils. In addition, increased C retention demonstrates an environmental benefit of this biochar production method. Biomass pyrolysis combined with clayey soil results in a biochar with a higher degree of aromaticity and higher thermal stability when compared to biomass pyrolysis alone. These characteristics give the biochar a recalcitrant character, without the necessity for steps related to the synthesis of specific mineral compounds, which reduces the economic and energy cost of the process.