Graphene oxide (GO) with a two-dimensional lamellar structure and single-atom thickness has exhibited advantages in water purification by stacking to a continuous membrane. However, a proper method to further increase the separation property of the GO membrane is still urgently needed. Besides, damage to the membrane during the fullscale application processes and the resulted consequential loss are prevalent problems need to be solved. Here, a hierarchically assembled GO composite membrane was developed that can achieve high-efficiency water purification performance and self-healing property via the synergistic effect of the metal− organic framework (MOF) and the coated hydrophilic layer of chitosan. The intercalated MOF effectively expanded the channel space of GO and endowed the channels with molecular-sieving property. Meanwhile, the coated chitosan layer can selectively adsorb water and achieve self-healing through the cross-linking reaction. The prepared GO composite membrane shows largely improved water flux (14.62 L m −2 h −1 bar −1 ), increased 344% than the water flux of the GO membrane, high rejection ratio (>99% for dyes), and good antifouling performance. In addition, the damaged GO composite membrane can recover its water flux (95%) and rejection ratio (96%) through a facile self-healing process.
Metal-organic frameworks (MOFs) have shown great potential in flame retardant applications; however, strategies for fully exploiting the advantages of MOFs in order to further enhance the flame retardant performance are still in high demand. Herein, a novel MOF composite was designed through the generated cooperative role of MOF (NH2-MIL-101(Al)) and a phosphorus-nitrogen-containing ionic liquid ([DPP-NC3bim][PMO]). The ionic liquid (IL) was composed of imidazole cation modified with diphenylphosphinic group (DPP) and phosphomolybdic acid (PMoA) anions, which can trap the degrading polymer radicals and reduce the smoke emission. The MOF acts as a porous host and can avoid the agglomeration of ionic liquid. Meanwhile, the -NH2 groups of NH2-MIL-101(Al) can increase the compatibility with epoxy resin (EP). The framework is expected to act as an efficient insulating barrier to suppress the flame spread. It was demonstrated that the MOF composite (IL@NH2-MIL-101(Al)) is able to effectively improve the fire safety of EP at low additions (3 wt. %). The LOI value of EP/IL@NH2-MIL-101(Al) increased to 29.8%. The cone calorimeter results showed a decreased heat release rate (51.2%), smoke production rate (37.8%), and CO release rate (44.8%) of EP/IL@NH2-MIL-101(Al) with respect to those of neat EP. This strategy can be extended to design other advanced materials for flame retardant.
Metal–organic frameworks (MOFs) exhibit highly designable properties and have been used in wide applications. To further improve their performance, the modification of MOFs is an effective method. However, the modification process is usually complicated. Besides, the sustainable use of MOFs is difficult to achieve due to the complicated recycling treatment. Herein, we designed a polyethyleneimine (PEI)-modified NH 2 -MIL-101(Al) composite (PEI@NH 2 -MIL-101(Al)). This composite showed excellent dye removal performance of methyl orange (MO, 89.4%) and Direct Red 80 (DR80, 99.8%). Remarkably, the dye removal application of PEI@NH 2 -MIL-101(Al) also acted as a modification process toward flame retardant application. Thus, the dye-adsorbed PEI@NH 2 -MIL-101(Al) composite (MO-PEI@NH 2 -MIL-101(Al) and DR80-PEI@NH 2 -MIL-101(Al)) was sustainably used as an effective flame retardant for an epoxy resin (EP) at low additions (4.0 wt %). The limiting oxygen values of EP/MO-PEI@NH 2 -MIL-101(Al) and EP/DR80-PEI@NH 2 -MIL-101(Al) increased to 26.5 and 26.7%, respectively. The heat release and the smoke production of dyes-PEI@NH 2 -MIL-101(Al)/EP were greatly reduced compared with those of EP. This strategy provides a simple and effective modification method for MOFs. Meanwhile, the modified MOF composite can achieve sustainable application, giving full play to the advantages of MOFs.
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