Ever increasing mine production capacity and mechanized operations enable advanced drilling equipment to be widely adopted in underground mines. In order to achieve satisfactory blasting performance in tunnel advance, there is a critical need to optimize the blasting technique to match the large deep-hole drilling capability. In this study, through theoretical analysis of tunnel blasting, the layout of cutting holes was found to be the key factor controlling the blasting performance. The deep-hole cutting effect was first investigated by analyzing the influence of the free surface of a hollow hole using the fluid-structure interaction modeling method in ANSYS/LS-DYNA. Then the rock dynamic evolution processes of blasting using a double-cavity grooving and a four-cavity grooving were compared and analyzed towards an understanding of the influence of the spacing and layout of cutting holes on the blasting performance. The comparison results show that four empty hole cut layouts yield larger effective free surface than that of the two empty hole cut layouts. This is because larger compensation space for breaking of rock and expansion of gas is more conducive to improving the energy utilization rate of explosives and thus improving the blasting performance and the footage of cyclic blasting. The results indicated that the blasting performance can be improved by reserving reasonable compensation space in the grooving area.
Due to the special properties of the ammonium salts, ammonium acetate and ammonium citrate were used to explore the best leaching conditions of rare earth with compound ammonium carboxylate. This paper explored the influence of the molar ratio, ammonium concentration, experimental temperature, and pH of the compound leaching agents on the leaching efficiency of rare earth and aluminum, and it analyzed the leaching process based on the leaching kinetics, which provides a new method for leaching rare earth from the weathered crust elution-deposited rare earth ore. The results showed that under the conditions where the molar ratio of ammonium acetate and ammonium citrate was 7:3 and the ammonium concentration was 0.15 mol/L, the leaching efficiency of rare earth was the highest when the pH of leaching agent was 4.0 and the experimental temperature was 313 K. Meanwhile, when CH3COONH4 and (NH4)3Cit were used to leach rare earth ore, the leaching reaction kinetics equation of rare earth and aluminum were obtained. In the temperature range of 283–323 K, the apparent activation energy of rare earth was 14.89 kJ/mol and that of aluminum was 19.17 kJ/mol. The reaction order of rare earth was 0.98 and that of aluminum was 0.79. The results were in accordance with the shrinking core model and indicate that the concentration of the leaching agent had a greater influence on rare earth than aluminum. This process can reduce the use of ammonium salt, and it is of great significance to extract rare earth elements from weathered crust elution-deposited rare earth ore and improve the utilization rate of resources.
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