In reduced TiO2, electronic transitions originating from the Ti(3+)-induced states in the band gap are known to contribute to the photoabsorption, being in fact responsible for the material's blue color, but the excited states accessed by these transitions have not been characterized in detail. In this work we investigate the excited state electronic structure of the prototypical rutile TiO2(110) surface using two-photon photoemission spectroscopy (2PPE) and density functional theory (DFT) calculations. Using 2PPE, an excited resonant state derived from Ti(3+) species is identified at 2.5 ± 0.2 eV above the Fermi level (EF) on both the reduced and hydroxylated surfaces. DFT calculations reveal that this excited state is closely related to the gap state at ∼1.0 eV below EF, as they both result from the Jahn-Teller induced splitting of the 3d orbitals of Ti(3+) ions in reduced TiO2. Localized excitation of Ti(3+) ions via 3d → 3d transitions from the gap state to this empty resonant state significantly increases the TiO2 photoabsorption and extends the absorbance to the visible region, consistent with the observed enhancement of the visible light induced photocatalytic activity of TiO2 through Ti(3+) self-doping. Our work reveals the physical origin of the Ti(3+) related photoabsorption and visible light photocatalytic activity in prototypical TiO2 and also paves the way for the investigation of the electronic structure and photoabsorption of other metal oxides.
Although it has been widely accepted that the crystal phase, morphology, and facet significantly influence the catalytic and photocatalytic activity of TiO2, establishing the correlation between structure and activity of heterogeneous reactions is very difficult because of the complexity of the structure. Utilizing ultrahigh vacuum (UHV) based temperature-programmed desorption (TPD) and density functional theory (DFT) calculations, we have successfully assessed the photoreactivity of two well characterized rutile surfaces ((011)-(2×1) and (110)-(1×1)) through examining the photocatalyzed oxidation of methanol. The photocatalytic products, such as formaldehyde and methyl formate, are the same on both surfaces under UV illumination. However, the reaction rate on (011)-(2×1) is only 42% of that on (110)-(1×1), which contradicts previous reports in aqueous environments where characterization of TiO2 structure is difficult. The discrepancy probably comes from the differences of the TiO2 structure in these studies. Our DFT calculations reveal that the rate-determining step of methanol dissociation on both surfaces is C–H scission,; however, the barrier of this elementary step on (011)-(2×1) is about 0.2 eV higher than that on (110)-(1×1) because of their distinct surface atomic configurations. The present work not only demonstrates the importance of surface structure in the photoreactivity of TiO2, but also provides an example for building the correlation between structure and activity using surface science techniques and DFT calculations.
Recycling awarded the silver: Ag(3)PO(4), a highly efficient photocatalyst, decomposes to the weak photocatalyst Ag during consecutive photocatalytic cycles. A facile and very mild wet chemical oxidation method was proposed, which involves the cooperation of H(2)O(2) with Na(2)HPO(4), to rejuvenate Ag(3)PO(4) from Ag as a recyclable highly efficient photocatalyst.
The search for excellent cathodes for lithium batteries is the main topic in order to meet the requirements of low cost, high safety, and high capacity in many real applications. β-MnO2, as a potential candidate, has attracted great attention because of its high stability and potential high capacity among all the phases. Because of the complexity of β-MnO2, some fundamental questions at the atomic level during the charge-discharge process, remain unclear. The lithiation process of β-MnO2 has been systematically examined by first-principles calculations along with cluster expansion techniques. Five stable configurations during the lithium intercalation process are firstly determined, and the electrochemical voltages are from 3.47 to 2.77 eV, indicating the strongly correlated effects of the β-MnO2-LiMnO2 system. During the lithiation process, the changes in the lattice parameters are not symmetric. The analysis of electronic structures shows that Mn ions are in the mixed valence states of Mn(3+) and Mn(4+) during the lithiation process, which results in Jahn-Teller distortion in Mn(3+)O6 octahedra. Such results uncover the intrinsic origin of the asymmetric deformation during the charge-discharge process, resulting in the irreversible capacity fading during cycling. From the analysis of the thermal reduction of delithiated LixMnO2, the formation of oxygen is thermodynamically infeasible in the whole extraction process. Our results indicate that β-MnO2 has great potential as a cathode material for high capacity Li-ion batteries.
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