Surface
coating of composite electrode has recently received increasing attention
and has been demonstrated to be effective in enhancing the electrochemical
performance of lithium ion battery (LIB) materials. In this work,
an electronic-insulating but ionic-conductive lithium carbonate (Li2CO3) is rationally selected as the unique coating
material for commercial LiCoO2 (LCO) cathode. Li2CO3 is a well-known constitute in conventional solid electrolyte
interface (SEI) layer, which can electrochemically protect the electrode.
The carbonate coating layer is deposited on LCO composite electrodes
via a facial magnetron sputtering approach. The sputtered Li2CO3 layer serves as an artificial SEI layer between the
active material and electrolyte and can impede the formation of the
primary SEI layer, which will permanently consume Li+ and
reduce the reversible capacity of the electrode. After a 10 min Li2CO3 coating, the capacity retention of the composite
electrode is improved from 64.4% to 87.8% when cycled at room temperature
in the potential range of 3.0–4.5 V vs Li/Li+ for
60 cycles. The obtained discharge capacity is extended to 161 mAh
g–1, which is 36% higher than the uncoated one (118
mAh g–1). When further increasing the charging potential
up to 4.7 V, or elevating the operation temperature to 55 °C,
the Li2CO3-coated LCO electrodes still display
remarkably improved cycling stability.
Surface modification of LiCoO2 is an effective method to improve its energy density and elongate its cycle life in an extended operation voltage window. In this study, ZnO was directly coated on as-prepared LiCoO2 composite electrodes via radio frequency (RF) magnetron sputtering. ZnO is not only coated on the electrode as thin film but also diffuses through the whole electrode due to the intrinsic porosity of the composite electrode and the high diffusivity of the deposited species. It was found that ZnO coating can significantly improve the cycling performance and the rate capability of the LiCoO2 electrodes in the voltage range of 3.0-4.5 V. The sample with an optimum coating thickness of 17 nm exhibits an initial discharge capacity of 191 mAh g(-1) at 0.2 C, and the capacity retention is 81% after 200 cycles. It also delivers superior rate performance with a reversible capacity of 106 mAh g(-1) at 10 C. The enhanced cycling performance and rate capability are attributed to the stabilized phase structure and improved lithium ion diffusion coefficient induced by ZnO coating as evidenced by X-ray diffraction, cyclic voltammetry, respectively.
Currently, many organic materials are being considered as electrode materials and display good electrochemical behavior. However, the most critical issues related to the wide use of organic electrodes are their low thermal stability and poor cycling performance due to their high solubility in electrolytes. Focusing on one of the most conventional carboxylate organic materials, namely lithium terephthalate Li 2 C 8 H 4 O 4 , we tackle these typical disadvantages via modifying its molecular structure by cation substitution. CaC 8 H 4 O 4 and Al 2 (C 8 H 4 O 4 ) 3 are prepared via a facile cation exchange reaction. Of these, CaC 8 H 4 O 4 presents the best cycling performance with thermal stability up to 570 °C and capacity of 399 mA·h·g -1 , without any capacity decay in the voltage window of 0.005-3.0 V. The molecular, crystal structure, and morphology of CaC 8 H 4 O 4 are retained during cycling. This cation-substitution strategy brings new perspectives in the synthesis of new materials as well as broadening the applications of organic materials in Li/Na-ion batteries.
The selection and optimization of coating material/approach for electrode materials have been under intensive pursuit to address the high-voltage induced degradation of lithium ion batteries. Herein, we demonstrate an efficient way to enhance the high-voltage electrochemical performance of LiCoO cathode by postcoating of its composite electrode with LiTiO (LTO) via magnetron sputtering. With a nanoscale (∼25 nm) LTO coating, the reversible capacity of LiCoO after 60 cycles is significantly increased by 40% (to 170 mAh g) at room temperature and by 118% (to 139 mAh g) at 55 °C. Meanwhile, the electrode's rate capability is also greatly improved, which should be associated with the high Li diffusivity of the LTO surface layer, while the bulk electronic conductivity of the electrode is unaffected. At 12 C, the capacity of the coated electrode reaches 113 mAh g, being 70% larger than that of the uncoated one. The surface interaction between LTO and LiCoO is supposed to reduce the space-charge layer at the LiCoO-electrolyte interface, which makes the Li diffusion much easier as evidenced by the largely enhanced diffusion coefficient of the coated electrode (an order of magnitude improvement). In addition, the LTO coating layer, which is electrochemically and structurally stable in the applied potential range, plays the role of a passivation layer or an artificial and friendly solid electrolyte interface (SEI) layer on the electrode surface. Such protection is able to impede propagation of the in situ formed irreversible SEI and thus guarantee a high initial columbic efficiency and superior cycling stability at high voltage.
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