Zeolitic nanotubes
Nanotubes generally have solid walls, but a low-dimensional version of zeolites now introduces porosity into such structures. Korde
et al
. used a structure-directing agent with a hydrophobic biphenyl group center connecting two long alkyl chains bearing hydrophilic bulky quaternary ammonium head groups to direct hydrothermal synthesis with silicon-rich precursors (see the Perspective by Fan and Dong). The nanotubes have a mesoporous central channel of approximately 3 nanometers and zeolitic walls with micropores less than 0.6 nanometers. Electron microscopy and modeling showed that the outer surface is a projection of a large-pore zeolite and the inner surface is a projection of a medium-pore zeolite. —PDS
The present work deals with the recovery of critical rare-earth elements (REEs) from acidic aqueous solutions. In doing so, we study the adsorption of these ions on ETS-10 titanosilicate. The experimental data are individually fitted with the Langmuir and Freundlich isotherms, and a high adsorption capacity for REEs is found. We further explore the competitive separation of Nd 3+ from Ni 2+ ions and Dy 3+ from Nd 3+ ions usually found in aqueous streams generated during the recycling of NiMH batteries and NdFeB permanent magnets, respectively, via adsorption using ETS-10.
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