A novel approach based on polydimethylsiloxane/graphene oxide/deep eutectic solvent (PDMS/GO/DES) sponge headspace solid phase extraction followed by GC-MS was successfully developed to determine the volatile components in cumin. The PDMS/GO/DES...
An adsorbent polydimethylsiloxane/graphene oxide/β‐cyclodextrin sponge, which possessed the merits of high surface area, chemical stability, environment friendly, and excellent extraction capacity, was successfully fabricated. Based on the advantages, a novel microwave‐assisted headspace solid‐phase extraction method for lavender essential oil using polydimethylsiloxane/graphene oxide/β‐cyclodextrin sponge as adsorbents was developed in this study. Various experimental parameters were studied. The optimal extraction conditions were as follows: 1 mg/mL as dopamine solution concentration, graphene oxide dosages of 30 mg, microwave power of 700 W, microwave irradiation time of 10 min, and desorption solvent of n‐hexane. Under the optimal extraction condition, linearities ranging from 10 to 800 ng were achieved for six representative compounds with a correlation coefficients value of >0.99. The intra‐day and inter‐day precisions were in the ranges of 0.40–1.56 and 0.67–2.56%, respectively. Finally, the proposed technique was applied to analyze essential oil constituents in 14 samples of three lavender varieties, and 48 compounds were identified. Lavender varieties were distinguished using principal component analysis and partial least squares discriminant analysis. The results showed that the method developed in this study is a novel, simple, and sensitive method for the determination of essential oil in complex plant samples.
Introduction: Due to the complexity and the low concentrations of volatile components in aromatic plants, sample pretreatment is an important step in the whole analytical procedure.Objective: This study aimed to propose a novel, sensitive and fast approach to determine the volatile components in lavender.
Methods: The 1-butyl-3-(propyltrimethoxysilane)imidazolium chloride ([BPtmsim]Cl) ionic liquid was introduced onto the surface of polydimethylsiloxane (PDMS) to prepare a novel PDMS/[BPtmsim]Cl sponge with large surface area, good sorption performance, and reusability. A solid-phase extraction method was developed based on PDMS/[BPtmsim]Cl sponge combined with gas chromatography-mass spectrometry (GC-MS).Results: The effects of the various experimental parameters on the extraction efficiency were investigated. The optimal conditions were [BPtmsim]Cl amount of 0.3 g, 1:4 as the mass ratio of PDMS/[BPtmsim]Cl to lavender sample, microwave power of 700 W, microwave time of 10 min, and n-hexane as the desorption solvent. The method validation results showed good linearity (10-800 μg/ml), high correlation coefficient (R 2 ≥ 0.9991), low limits of detection (1.73-2.50 ng/μl), and limits of quantification (4.10-5.11 ng/μl). The interday and intraday precision with relative standard deviation (RSD) values were below 1.93% and 4.71%, respectively. Under the optimal extraction conditions, 16 lavender samples from three different species were analysed and a total of 57 volatile compounds were identified. The correlation between different species of lavender and volatile components was explored using principal component analysis (PCA) and partial least squares-discriminant analysis (PLS-DA).
Conclusion:The results showed that PDMS/[BPtmsim]Cl extraction is a rapid, highly efficient, and sensitive technique for the determination of volatile components in complex plant samples.
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