The magnetic properties of carbon materials are at present the focus of intense research effort in physics, chemistry and materials science due to their potential applications in spintronics and quantum computing. Although the presence of spins in open-shell nanographenes has recently been confirmed, the ability to control magnetic coupling sign has remained elusive but highly desirable. Here, we demonstrate an effective approach of engineering magnetic ground states in atomically precise open-shell bipartite/nonbipartite nanographenes using combined scanning probe techniques and mean-field Hubbard model calculations. The magnetic coupling sign between two spins was controlled via breaking bipartite lattice symmetry of nanographenes. In addition, the exchange-interaction strength between two spins has been widely tuned by finely tailoring their spin density overlap, realizing a large exchange-interaction strength of 42 meV. Our demonstrated method provides ample opportunities for designer above-room-temperature magnetic phases and functionalities in graphene nanomaterials.

No abstract

Non-Fermi liquid behavior and pseudogap formation are among the most well-known examples of exotic spectral features observed in several strongly correlated materials such as the hole-doped cuprates, nickelates, iridates, ruthenates, ferropnictides, doped Mott organics, transition metal dichalcogenides, heavy fermions, dand f -electron metals, etc. We demonstrate that these features are inevitable consequences when fermions couple to an unconventional Bose metal [1] mean field consisting of lower-dimensional coherence. Not only do we find both exotic phenomena, but also a host of other features that have been observed e.g. in the cuprates including nodal anti-nodal dichotomy and pseudogap asymmetry(symmetry) in momentum(real) space. Obtaining these exotic and heretofore mysterious phenomena via a mean field offers a simple, universal, and therefore widely applicable explanation for their ubiquitous empirical appearance.

Non-Fermi liquid behavior and pseudogap formation are among the most well-known examples of exotic spectral features observed in several strongly correlated materials such as the hole-doped cuprates, nickelates, iridates, ruthenates, ferropnictides, doped Mott organics, transition metal dichalcogenides, heavy fermions, $d$- and $f$-electron metals, etc. We demonstrate that these features are inevitable consequences when fermions couple to an unconventional Bose metal~\cite{hegg2021bose} mean field consisting of lower-dimensional coherence. Not only do we find both exotic phenomena, but also a host of other features that have been observed e.g. in the cuprates including nodal anti-nodal dichotomy and pseudogap asymmetry(symmetry) in momentum(real) space. Obtaining these exotic and heretofore mysterious phenomena via a mean field offers a simple, universal, and therefore widely applicable explanation for their ubiquitous empirical appearance.