A new metal-organic framework with potential for adsorptive separation of methane from carbon dioxide, acetylene, ethylene, and ethane established by simulated breakthrough experiments Duan, X.; Zhang, Q.; Cai, J.; Yang, Y.; Cui, Y.; He, Y.; Wu, C.; Krishna, R.; Chen, B.; Qian, G. Disclaimer/Complaints regulationsIf you believe that digital publication of certain material infringes any of your rights or (privacy) interests, please let the Library know, stating your reasons. In case of a legitimate complaint, the Library will make the material inaccessible and/or remove it from the website. Please Ask the Library: http://uba.uva.nl/en/contact, or a letter to: Library of the University of Amsterdam, Secretariat, Singel 425, 1012 WP Amsterdam, The Netherlands. You will be contacted as soon as possible.

To immobilize open Cu2+ sites and tune suitable pore spaces, we have realized a doubly interpenetrated metal–organic framework (MOF) [Cu2L(H2O)2]·(DMF)6·H2O (ZJU-30, ZJU = Zhejiang University; H4L = biphenyl-3,3′,5,5′-tetra-(phenyl-4-carboxylic) acid; DMF = N,N-dimethylformamide) for the highly selective separation of C2 hydrocarbons over C1 methane with the Henry law’s selectivities from 9.58 to 29.8 in the temperature range from 273 to 298 K.

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A novel microporous MOF ZJU-16 exhibited high thermal and chemical stability and moderately high selective separation of C2H2/CH4 and CO2/CH4.