Graphene and functionalized graphene are promising candidates as ultrathin solid lubricants for dealing with the adhesion and friction in micro- and nanoelectromechanical systems (MEMS and NEMS). Here, the dynamic friction and adhesion characteristics of pristine graphene (PG), graphene oxide (GO), and fluorinated graphene (FG) were comparatively studied using atomic force microscopy (AFM). The friction as a function of load shows nonlinear characteristic on GO with strong adhesion and linear characteristic on PG and FG with relatively weak adhesions. An adhesion enhancement phenomenon that the slide-off force after dynamic friction sliding is larger than the pull-off force is observed. The degree of adhesion enhancement increases with the increasing surface energy, accompanied by a corresponding increase in transient friction strengthening effect. The dynamic adhesion and friction enhancements are attributed to the coupling of dynamic tip sliding and surface hydrophilic properties. The atomic-scale stick-slip behaviors confirm that the interfacial interaction is enhanced during dynamic sliding, and the enhancing degree depends on the surface hydrophilic properties. These findings demonstrate the adhesive strength between the contact surfaces can be enhanced in the dynamic friction process, which needs careful attention in the interface design of MEMS and NEMS.
The current-carrying nanofriction characteristics play an important role in the performance, reliability, and lifetime of graphene-based micro/nanoelectromechanical systems and nanoelectronic devices. The atomic-scale friction characteristics of graphene were investigated using conductive atomic force microscopy by applying positive-bias and negative-bias voltages. The atomic-scale friction increased with applied voltages. Also, the friction under positive-bias voltages was lower than under negative-bias voltages, and the friction difference increased with the voltages. The different frictional behaviors resulted from the inherent work function difference and the water molecules between the tip and graphene. The applied voltages amplified the effect of the work function difference on the friction, and the water molecules played different roles under negative-bias and positive-bias voltages. The friction increased rapidly with the continuous increase of negative-bias voltages due to the electrochemical oxidation of graphene. Nevertheless, the friction under positive-bias voltages remained low and the structure of graphene was unchanged. These experimental observations were further explained by modeling the atomic-scale friction with a modified Prandtl−Tomlinson model. The model allowed the determination of the basic potential barrier and the voltage-induced potential barrier between the tip and graphene. The calculation based on the model indicated that the negative-bias voltages induced a larger potential barrier than the positive-bias voltages. The studies suggest that graphene can show a better lubricant performance by working as a lubricant coating for the cathodes of the sliding electrical contact interfaces.
Graphene shows great potential applications as a solid lubricant in micro- and nanoelectromechanical systems (MEMS/NEMS). An atomic-scale friction strengthening effect in a few initial atomic friction periods usually occurred on few-layer graphene. Here, velocity dependent friction strengthening was observed in atomic-scale frictional behavior of graphene by atomic force microscopy (AFM). The degree of the friction strengthening decreases with the increase of velocity first and then reaches a plateau. This could be attributed to the interaction potential between the tip and graphene at high velocity which is weaker than that at low velocity, because the strong tip-graphene contact interface needs a longer time to evolve. The subatomic-scale stick-slip behavior in the conventional stick-slip motion supports the weak interaction between the tip and graphene at high velocity. These findings can provide a deeper understanding of the atomic-scale friction mechanism of graphene and other two-dimensional materials.
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