Although organic light-emitting molecules have received a growing attention and applicability in modern bioimaging science, the design and control of complex photoluminescent properties in unimolecularly selective imaging remains a challenging topic. Considering that tunable multipathway imaging can be advantagedly connected with treatment processes in therapy, the integration of an azulene and a cyanostyryl moiety into one skeleton is carried out for the generation of in situ stimuli-responsive luminescent materials, with the aim to achieve tunable and effective emissions in distinct channels through smart molecular design on a single-molecular platform. This strategy takes advantage of 1) the Z/E isomerization of the cyanostyryl unit that can vary the push-pull effect of the substitution on azulene, accompanied by altering absorption and emission of individual excited states, and 2) an optimized excited-state regulation for opening a near infrared emissive channel and making up for a controllable dual-pathway luminescent system together with the utilization of visible emission. As exemplified by a demonstration of manipulating the luminescence at the cell level, the materials exhibit a superior application potential for unimolecularly selective imaging, labeling and probing events.
Dance and music are expressive art forms. Previous behavioural studies have reported that dancers/musicians show a better sensorimotor ability and emotional representation of others. However, the neural mechanism behind this phenomenon is not completely understood. Recently, intensive researches have identified that the insula is highly enrolled in the empathic process. Thus, to expand the knowledge of insular function associated with empathy under the dance/music training background, we mapped the insular network and its associated brain regions in 21 dancers, 20 musicians, and 24 healthy controls using resting-state functional connectivity (FC) analysis. Whole brain voxel-based analysis was performed using seeds from the posterior insula (PI), the ventral anterior insula (vAI), and the dorsal anterior insula (dAI). The training effects of dance and music on insular subnetworks were then evaluated using one-way analysis of variance ANOVA. Increased insular FC with those seeds was found in dancers/musicians, including PI and anterior cingulated cortex (ACC), vAI and middle temporal gyrus (MTG) and middle cingulated cortex (MCC), and dAI and ACC and MTG. In addition, significant associations were found between discrepant insular FC patterns and empathy scores in dancers and musicians. These results indicated that dance/music training might enhance insular subnetwork function, which would facilitate integration of intero/exteroceptive information and result in better affective sensitivity. Those changes might finally facilitate the subjects’ empathic ability.
Upon irradiation with nanosecond pulsed UV laser, surface periodic microstructure and photoorientation occurred simultaneously on the azobenzene functionalized liquid crystalline dendrimer films. The
orientation of azo groups was perpendicular to the polarization of pulsed laser and dependent on the laser fluence.
The in-plane orientation of azo groups presented parabola-shaped behavior with the increase of laser fluences.
The out-of-plane reorientation of azo groups was closely related to thermal effect induced in the procedure of
nanosecond pulsed irradiation, which led to the transformation of phase state of azo groups from smectic liquid
crystal phase to isotropic phase. Annealing of irradiated film at its liquid crystalline temperature resulted in
dramatic enhancement of in-plane orientation and out-of-plane redistribution of azo groups. Liquid crystal alignment
on the irradiated film was controlled by a cooperative effect of surface topography and anisotropic molecular
orientation simultaneously. Both factors can be modulated by annealing treatment. After annealing, the alignment
of liquid crystal molecules can be changed from the direction of surface microgrooves to that of the molecular
orientation.
Pressure ripples in electric power steering (EPS) systems can be caused by the phase lag between the driver s steering torque and steer angle, the nonlinear frictions, and the disturbances from road and sensor noise especially during high-frequency maneuvers. This paper investigates the use of the robust fuzzy control method for actively reducing pressure ripples for EPS systems. Remarkable progress on steering maneuverability is achieved. The EPS dynamics is described with an eight-order nonlinear state-space model and approximated by a Takagi-Sugeno (T-S) fuzzy model with time-varying delays and external disturbances. A stabilization approach is then presented for nonlinear time-delay systems through fuzzy state feedback controller in parallel distributed compensation (PDC) structure. The closed-loop stability conditions of EPS system with the fuzzy controller are parameterized in terms of the linear matrix inequality (LMI) problem. Simulations and experiments using the proposed robust fuzzy controller and traditional PID controller have been carried out for EPS systems. Both the simulation and experiment results show that the proposed fuzzy controller can reduce the torque ripples and allow us to have a good steering feeling and stable driving.
A compact see-through three-dimensional head-mounted display (3D-HMD) is proposed and investigated in this paper. Two phase holograms are analytically extracted from the object wavefront and uploaded on different zones of the spatial light modulator (SLM). A holographic grating is further used as the frequency filter to couple the separated holograms together for wavefront modulation. The developed preliminary prototype has a simple optical facility and a compact structure (133.8mm × 40.4mm × 35.4mm with a 47.7mm length viewing accessory). Optical experiments demonstrated that the proposed system can present 3D images to the human eye with full depth cues. Therefore, it is free of the accommodation-vergence conflict and visual fatigue problem. The dynamic display ability is also tested in the experiments, which provides a promising potential for the true 3D interactive display.
We report experimental research on laser plasma interaction (LPI) conducted in Shenguang laser facilities during the past ten years. The research generally consists of three phases: (1) developing platforms for LPI research in mm-scale plasma with limited drive energy, where both gasbag and gas-filled hohlraum targets are tested; (2) studying the effects of beam-smoothing techniques, such as continuous phase plate and polarization smoothing, on the suppression of LPI; and (3) exploring the factors affecting LPI in integrated implosion experiments, which include the laser intensity, gas-fill pressure, size of the laser-entrance hole, and interplay between different beam cones. Results obtained in each phase will be presented and discussed in detail.
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