Redox-active organic molecules have drawn extensive interests in redox flow batteries (RFBs) as promising active materials, but employing them in nonaqueous systems is far limited in terms of useable capacity and cycling stability. Here we introduce azobenzene-based organic compounds as new active materials to realize high-performance nonaqueous RFBs with long cycling life and high capacity. It is capable to achieve a stable long cycling with a low capacity decay of 0.014% per cycle and 0.16% per day over 1000 cycles. The stable cycling under a high concentration of 1 M is also realized, delivering a high reversible capacity of~46 Ah L −1. The unique lithium-coupled redox chemistry accompanied with a voltage increase is observed and revealed by experimental characterization and theoretical simulation. With the reversible redox activity of azo group in π-conjugated structures, azobenzene-based molecules represent a class of promising redox-active organics for potential grid-scale energy storage systems.
Band degeneracy is effective in optimizing the power factors of thermoelectric (TE) materials by enhancing the Seebeck coefficients. In this study, we demonstrate this effect in model systems of layered oxyselenide family by the density functional theory (DFT) combined with semi-classical Boltzmann transport theory. TE transport performance of layered LaCuOSe and BiCuOSe are fully compared. The results show that due to the larger electrical conductivities caused by longer electron relaxation times, the n-type systems show better TE performance than p-type systems for both LaCuOSe and BiCuOSe. Besides, the conduction band degeneracy of LaCuOSe leads to a larger Seebeck coefficient and a higher optimal carrier concentration than n-type BiCuOSe, and thus a higher power factor. The optimal figure of merit (ZT) value of 1.46 for n-type LaCuOSe is 22% larger than that of 1.2 for n-type BiCuOSe. This study highlights the potential of wide band gap material LaCuOSe for highly efficient TE applications, and demonstrates that inducing band degeneracy by cations substitution is an effective way to enhance the TE performance of layered oxyselenides.
Aqueous redoxflowbatteries (RFBs) are promising alternatives for large-scale energy storage.H owever,n ew organic redox-active molecules with good chemical stability and high solubility are still desired for high-performance aqueous RFBs due to their lowc rossover capability and high abundance.W er eport azobenzene-based molecules with hydrophilic groups as new active materials for aqueous RFBs by utilizing the reversible redox activity of azo groups.B y rationally tailoring the molecular structure of azobenzene,the solubility is favorably improved from near zero to 2Mdue to the highly charged asymmetric structure formed in alkaline environment. DFT simulations suggest that the concentrated solution stability can be enhanced by adding hydrotropic agent to form intermolecular hydrogen bonds.T he demonstrated RFB exhibits long cycling stability with acapacity retention of 99.95 %per cycle over 500 cycles.Itpresents aviable chemical design route towards advanced aqueous RFBs.
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