Polylactide-based polyurethane shape memory nanocomposites (Fe 3 O 4 /PLAUs) with fast magnetic responsiveness are presented. For the purpose of fast response and homogeneous dispersion of magnetic nanoparticles, oleic acid was used to improve the dispersibility of Fe 3 O 4 nanoparticles in apolymer matrix. A homogeneous distribution of Fe 3 O 4 nanoparticles in the polymer matrix was obtained fornanocomposites with low Fe 3 O 4 loading content. A smallagglomeration was observed fornanocomposites with 6 wt% and 9 wt% loading content, leading to a smalldecline in themechanical properties. PLAU and its nanocomposites have glass transition around 52 °C, which can be used as the triggering temperature. PLAU and its nanocomposites have shape fixity ratios above 99%, shape recovery ratios above 82% for the first cycle and shape recovery ratios above 91% for the second cycle. PLAU and its nanocomposites alsoexhibit a fast water bath or magnetic responsiveness. The magnetic recovery time decreases with anincrease inthe loading content of Fe 3 O 4 nanoparticles due to animprovement in heating performance for increased weight percentage of fillers. The nanocomposites have fast responses in an alternating magnetic field and have potential applicationin biomedical areas such as intravascular stent.
A series of random copolymers (PCLAs) were synthesized by ring-opening polymerization of D,L-lactide (LA) and ε-caprolactone (CL) with different molar ratios. PCLA based polyurethanes (PCLAUs) were obtained by chain-extending of PCLA and polytetramethylene ether (PTMEG) with hexamethylene diisocyanate (HDI). All the PCLAUs exhibit good shape memory properties with high shape fixity ratios above 98% and shape recovery ratios above 82% in the first cycle and 91% in the second cycle. PCLAUs with less CL content show faster recovery speed and PCLAUs with more CL content show higher shape recovery ratio. The trigger temperature can be tuned or controlled around body temperature by adjusting the molar ratio of LA to CL. The PCLAUs have potential applications in implant biomedical devices, especially for minimally invasive deployable devices.
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