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Two-dimensional (2D) bismuth(iii) sulfide (BiS) nanosheets as non-toxic graphene-like nanomaterials were successfully fabricated by a facile liquid phase exfoliation (LPE) method. A robust photodetector employing a BiS nanosheet film has been fabricated for the first time via a facile fabrication process on an ITO-coated glass. UV-Vis and Raman spectroscopy techniques were carried out and they confirmed the inherent optical and physical properties of BiS nanosheets. Photoelectrochemical (PEC) measurements demonstrate that a significantly higher photocurrent density (42 μA cm) and enhanced photoresponsivity (210 μA W), at a lower bias potential in alkaline solution, of the BiS nanosheet-based photodetector are achieved, compared with those of other 2D nanomaterial-based photodetectors under light irradiation. Furthermore, the as-prepared BiS nanosheet-based photodetector not only exhibits an appropriate capacity of self-driven broadband and high-performance photoresponse but also displays strong long-term stability of the ON/OFF switching behaviour without any external protection in alkaline solutions. Because of facile synthesis via a LPE method, a higher photocurrent density and photoresponsivity, self-driven performance and long-term stability of the BiS nanosheet-based photodetector at a lower bias potential in alkaline solutions, the present work can provide fundamental acknowledgement of the high performance of this new kind of PEC-type 2D nanosheet-based photodetector.

Non-layered tellurium (Te) is a promising material for applications in transistor and optoelectronic devices for its advantages in excellent intrinsic electronic and optoelectronic properties. However, the poor photodetection performance and relatively uncertain stability of tellurene under ambient conditions greatly limit the practical applications. In order to improve the performance of tellurene-based materials, Te@Se roll-to-roll nanotubes with different selenium (Se) contents synthesized by epitaxial growth of Se on Te nanotubes are, for the first time, employed to fabricate working electrodes for photoelectrochemical (PEC)-type broadband photodetection. They exhibit not only a preferably enhanced capacity for self-powered broadband photodetection but also significantly improved photocurrent density and stability in various aqueous environments (HCl, NaCl, and KOH solutions), compared to tellurene-based photodetectors. It is anticipated that the present work can open up new possibilities for high-performance tellurene-based optoelectronic devices.

Black-phosphorus-analogue tin monosulfide was successfully introduced to resolve the instability issue of black phosphorus.

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In order to effectively realize and control the critical coupling, a graphene-based hyperbolic metamaterial has been proposed to replace the absorbing thin film in the critically coupled resonance structure. Our calculations demonstrate that the critical coupling effect (near-perfect light absorption) can be achieved at the near-infrared wavelength by using this layered structure, while the critical coupling frequency can be tuned by varying the Fermi energy level of graphene sheets via electrostatic biasing. Moreover, we show that the critical coupling frequency can be tuned by changing the thickness of the dielectric or layer number of the graphene sheets in the unit cell of the graphene-dielectric HMM. The optimization performance has also been indicated, which may offer an opportunity towards the experimental designs of high efficient graphene based critical coupling devices.

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