For the rapid development of the hydrogen economy, a reliable and low-cost hydrogen sensor appears to be extremely important. Here, we first show that a palladium film deposited on polydimethylsiloxane (PDMS) can obtain an exceedingly high-reflectance contrast of 25.78 over the entire visible band upon exposure to 4 vol% hydrogen gas (H2) mixed with nitrogen gas. This high-reflectance contrast results from the surface deformation induced by the volume inflation after exposure to H2, leading to the transition of the near-specular surface to a diffusing surface. In addition, a change in brightness is readable by naked eye upon exposure to H2 with various concentrations from 0.6 to 1 vol% under the illumination of a fluorescent tube. Furthermore, this sensor possesses an excellent recyclability and quick response time of a few seconds. Compared with Pd nanostructure-based hydrogen sensors, this visual, high-contrast and low-cost sensor is of great potential for practical hydrogen sensing.
Plasmonic nanostructures offer an enticing prospect in many applications, ranging from lasing to biosensing, due to their unrivaled light concentration beyond the diffraction limit. However, this promise is substantially undercut by the intrinsically high losses in metals. Here, an experimental ultra‐high‐Q plasmon resonance with a linewidth down to 2 nm (Q‐factor ≈ 350) and a resonance intensity of 51% in an ultrasmooth gold nanogroove array is reported. Such an experimental ultranarrow resonance arises from two key factors. First, a geometrical‐induced coupling between the Fabry–Pérot and Wood's anomaly modes significantly suppresses the groove array's radiative damping. Second, an ultrasmooth gold surface fabricated by template stripping minimizes its surface scattering and grain boundary scattering. Benefiting from this ultranarrow resonance, a figure of merit (FOM) of 284 and an FOM* of 617 in refraction index (RI) sensing under normally incident detection are demonstrated, the former of which is the record FOM in all reported broad‐RI‐range plasmonic RI sensors. The array is further demonstrated as a surface thickness sensor for detecting mercaptocarboxylic acids with the surface sensitivity of 0.18 nm/CH2, which suggests that the array is a promising platform for thickness detection of surface analytes and label‐free biomedical sensing.
Manipulating light in sub-10-nm or subnanometer metal nanogaps is crucial to study the strong interaction between electromagnetic waves and matters. However, the fabrication of metallic nanogaps with precisely controlled size and high-throughput still remains a challenge. Here, we developed an approach to actively control the gap distance between adjacent metal nanoparticles from 140 nm to sub-10-nm or even 0 nm via mechanical stretching process. To demonstrate this method, we manufactured the gold disk arrays in a square lattice on the polydimethylsiloxane (PDMS) substrate through interference lithography and gold deposition, and sub-10-nm interparticle gap was achieved as exerting a strain of 100% to the PDMS substrate. Transmission spectra show a remarkable red shift of the dipole resonance with narrowing gap from 140 nm to sub-10-nm. Importantly, a universal scaling law between the gap distance in nanoscale and the stretching amount of PDMS substrate in macroscopic scale were demonstrated experimentally and theoretically. Our method can tune the gap distance continuously and reversibly, suggesting potential applications in surface-enhanced Raman scattering, single photon emitter and quantum tunneling of electric charge.
Low-cost hydrogen sensors, designed for ultrasensitive, reliable, and rapid identification of hydrogen gas (H 2 ), are extremely desired in almost all hydrogen-related applications in the forthcoming hydrogen economy, including crude oil refinement, hydrogen-fueled vehicles, and molecular hydrogen therapy. Here, we first report on the experimental realization of an ultrasensitive optical hydrogen sensor based on a new type of flexible palladium (Pd) nanogroove array. Each groove can be driven synchronously by absorbed hydrogen, with the assistance of the underneath elastic substrate, to mechanically reconfigure itself and thus amplify the spectral shift of plasmon resonance for hydrogen sensing. Our experimental results show a plasmon resonance with a narrow line width of 74 nm, which has a wavelength shift of 18 nm after exposed to 4% H 2 in nitrogen gas (N 2 ). In addition, the extremely high relative reflectance change of 400% was achieved, giving rise to an ultralow H 2 (in N 2 ) detection limit of 0.1% and sensing resolution of 0.013% in the low H 2 volume concentration regime. Meantime, exposure to H 2 causes a rapid and reversible change in reflectance on a time scale of seconds. This pronounced performance suggests that our flexible Pd nanogroove array provides a promising optical hydrogen detection scheme for practical applications.
Cephalopods offer a fascinating dynamic reflecting system to create desired colors and patterns through contracting and releasing their soft skins in response to environmental stimuli. Inspired by this natural display strategy, we designed a novel dynamic reflecting system based on pneumatic micro/nanoscale surface morphing. This system consists of a thin metal skin/elastomer bilayer modulated by a microfluidic-based gas injector. Benefited from the “wrinkled–specular” transition of the metal’s surface under a small pneumatic actuation (4 kPa), an unprecedented reflectance contrast of 93 for broad-band (500–750 nm) modulation is achieved. This remarkable response also has excellent cycle stability (>2500 times) and fast response time (∼0.2 s). These advantages enable a robust and ultrasensitive optical gas pressure sensor with a sensitivity of 178 kPa–1, which is 3–4 orders of magnitude higher than those of conventional optical gas pressure sensors based on either a Fabry–Pérot interferometer or a Mach–Zehnder interferometer. Moreover, as proof-of-concept applications, we also experimentally demonstrated a curvature-variable convex mirror and noniridescent dynamic display, suggesting that our pneumatically dynamic reflecting system will potentially broaden the applications in adaptive optical devices, sensors, and displays.
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