Developing the technology for high yielding photocatalytic hydrogen evolution reactions is an important challenge. Development and optimization of photocatalytic junctions is a likely route for achieving this if heterojunctions with suitable band alignments can be achieved in sufficiently high‐density form. Here, a novel anatase‐TiO2/H‐rutile‐TiO2 heterophase homojunction system with near optimum energy band alignment is reported. The resulting as‐prepared catalyst exhibits an excellent photocatalytic hydrogen evolution rate of 29.63 mmol g–1 h–1 under UV–vis light irradiation and an outstanding apparent quantum efficiency of 45.6% at 365 nm. The significant improvement is ascribed to near perfect lattice matching in combination with the rapid separation and transfer of photogenerated carriers in anatase‐TiO2/H‐rutile‐TiO2 heterophase homojunctions. In situ X‐ray photoelectron spectroscopy, electron spin resonance spin‐trapping tests, femtosecond transient absorption spectroscopy, steady‐state surface photovoltage spectroscopy, and transient‐state surface photovoltage with additional ex situ characterizations and theoretical calculations show that the mechanism is enhanced transfer of photogenerated carriers in the anatase‐TiO2/H‐rutile‐TiO2 catalyst. This work provides a pathway for enhancing photocatalytic performance through optimization of heterojunctions.
Scheme 1. Schematic Illustration of a) Z-scheme in natural photosynthesis, b) Z-scheme in an artificial photosynthetic system, c) S-scheme, d) twin S-scheme artificial photosynthetic system before and after contact, and under illumination. e) Schematic diagram of electrostatic self-assembly of material.
Photocatalytic Hydrogen Evolution
In article number 2200298 Xiaoqiang Cui and co‐workers report a novel anatase‐TiO2/H‐rutile‐TiO2 heterophase homojunction with near optimum energy band alignment. The resulting catalyst exhibits an excellent photocatalytic hydrogen evolution rate of 29.63 mmol g−1 h−1 and an outstanding apparent quantum efficiency of 45.6%. The significant improvement is ascribed to near perfect lattice matching in combination with the rapid separation and transfer of photogenerated carriers.
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