Being conductive and flexible, 2D transition metal nitrides and carbides (MXenes) can serve in Li-S batteries as sulfur hosts to increase the conductivity and alleviate the volume expansion. However, the surface functional groups, such as OH and F, weaken the ability of bare MXenes in the chemisorption of polysulfides. Besides, they create numerous hydrogen bonds which make MXenes liable to restack, resulting in substantial loss of active area and, thus, inaccessibility of ions and electrolyte. Herein, a facile, one-step strategy is developed for the growth of TiO quantum dots (QDs) on ultrathin MXene (Ti C T ) nanosheets by cetyltrimethylammonium bromide-assisted solvothermal synthesis. These QDs act as spacers to isolate the MXene nanosheets from restacking, and preserve their 2D geometry which guarantees larger electrode-electrolyte contact area and higher sulfur loading. The stronger adsorption energy of polysulfides with TiO (than with Ti C T ), as proven by density functional theory calculations, is essential for better on-site polysulfide retention. The ultrathin nature and protected conductivity ensure rapid ion and electron diffusion, and the excellent flexibility maintains high mechanical integrity. In result, the TiO QDs@MXene/S cathode exhibits significantly improved long-term cyclability and rate capability, disclosing a new opportunity toward fast and stable Li-S batteries.

A novel hybrid, composed of Co3O4quantum dots supported on Ti3C2Tx(MXene) nanosheets, exhibits a strong synergetic effect, and shows superior lithium storage (capacity = 766.5 mA h g−1at 2 A g−1after 400 cycles) and oxygen evolution (overpotential = 340 mV at 10 mA cm−2) activities.

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A facile and elegant self-organization strategy is proposed to decorate V2O5 nanosheets with Ag nanoparticles and TiO2 nanorods simultaneously.