piperidine-3-carboxylic acid), with intrinsic proton conductivity has been synthesized and characterized.Structure analysis shows that compound 1 possesses protonated tertiary amines as proton carriers and hydrogen-bonding chains served as proton-conducting pathways. Further, MOF-polymer composite membranes have been fabricated via assembling polymer PVP with different contents of rod-like 1 submicrometer crystals. Interestingly, the proton conductivity of this composite membrane containing 50 wt% 1 is rapidly increased, compared with that of pure submicrometer crystals at 298 K and $53% RH. Therefore, it is feasible to introduce humidification of PVP into composite membranes to enhance low-humidity proton conductivity; and humidified PVP with adsorbed water molecules plays an important role in proton conduction indicated by the results of water physical sorption and TG/DTG analyses. This study may offer a facile strategy to prepare a variety of solid electrolyte materials with distinctive proton-conducting properties under a low humidity.

The separation of acetylene from ethylene is a crucial process in the petrochemical industry, as even small acetylene impurities can lead to premature termination of ethylene polymerization. Herein, we present the synthesis of a robust, crystalline naphthalene diimide porous aromatic framework via imidization of linear naphthalene-1,4,5,8-tetracarboxylic dianhydride and triangular tris­(4-aminophenyl)­amine. The resulting material, PAF-110, exhibits impressive thermal and long-term structural stability, as indicated by thermogravimetric analysis and powder X-ray diffraction characterization. Gas adsorption characterization reveals that PAF-110 has a capacity for acetylene that is more than twice its ethylene capacity at 273 K and 1 bar, and it exhibits a moderate acetylene selectivity of 3.9 at 298 K and 1 bar. Complementary computational investigation of each guest binding in PAF-110 suggests that this affinity and selectivity for acetylene arises from its stronger electrostatic interaction with the carbonyl oxygen atoms of the framework. To the best of our knowledge, PAF-110 is the first crystalline porous organic material to exhibit selective adsorption of acetylene over ethylene, and its properties may provide insight into the further optimized design of porous organic materials for this key gas separation.

Porous organic frameworks (POFs) as an important subclass of nanoporous materials are of great interest in materials science. In recent years, the discovery and creation of POFs with excellent properties for advanced applications have attracted much attention and intensive efforts have been contributed to this field. As a result, the design of materials with multi-functionalities is an ever-pursued dream of materials scientists and engineers. In this respect, a new concept based on topology chemistry is introduced for the rational and targeted synthesis of POF materials. The present feature article provides an overview of the relationship between building blocks or starting monomers, underlying topological nets, and pre-determined structures. Several important nets are included successively from one to three dimensions. In addition, special emphasis is given to the advanced applications of designed POF materials in the current paper.

Hydrogen‐based energy is a promising renewable and clean resource. Thus, hydrogen selective microporous membranes with high performance and high stability are demanded. Novel NH2‐MIL‐53(Al) membranes are evaluated for hydrogen separation for this goal. Continuous NH2‐MIL‐53(Al) membranes have been prepared successfully on macroporous glass frit discs assisted with colloidal seeds. The gas sorption ability of NH2‐MIL‐53(Al) materials is studied by gas adsorption measurement. The isosteric heats of adsorption in a sequence of CO2 > N2 > CH4 ≈ H2 indicates different interactions between NH2‐MIL‐53(Al) framework and these gases. As‐prepared membranes are measured by single and binary gas permeation at different temperatures. The results of singe gas permeation show a decreasing permeance in an order of H2 > CH4 > N2 > CO2, suggesting that the diffusion and adsorption properties make significant contributions in the gas permeation through the membrane. In binary gas permeation, the NH2‐MIL‐53(Al) membrane shows high selectivity for H2 with separation factors of 20.7, 23.9 and 30.9 at room temperature (288 K) for H2 over CH4, N2 and CO2, respectively. In comparison to single gas permeation, a slightly higher separation factor is obtained due to the competitive adsorption effect between the gases in the porous MOF membrane. Additionally, the NH2‐MIL‐53(Al) membrane exhibits very high permeance for H2 in the mixtures separation (above 1.5 × 10−6 mol m−2 s−1 Pa−1) due to its large cavity, resulting in a very high separation power. The details of the temperature effect on the permeances of H2 over other gases are investigated from 288 to 353 K. The supported NH2‐MIL‐53(Al) membranes with high hydrogen separation power possess high stability, resistance to cracking, temperature cycling and show high reproducibility, necessary for the potential application to hydrogen recycling.

A “pure” porous carbon, lacking any elemental doping, exhibits excellent activity of oxygen reduction.

Most metal–organic‐framework‐ (MOF‐) based hybrid membranes face the challenge of low gas permeability in CO2 separation. This study presents a new strategy of interweaving UiO‐66 and PIM‐1 to build freeways in UiO‐66‐CN@sPIM‐1 membranes for fast CO2 transport. In this strategy, sPIM‐1 is rigidified via thermal treatment to make polymer voids permanent, and concurrently polymer chains are mutually linked onto UiO‐66‐CN crystals to minimize interfacial defects. The pore chemistry of UiO‐66‐CN is kept intact in hybrid membranes, allowing full utilization of MOF pores and selective adsorption for CO2. Separation results show that UiO‐66‐CN@sPIM‐1 membranes possess exceptionally high CO2 permeability (15433.4–22665 Barrer), approaching to that of UiO‐66‐NH2 crystal (65–75% of crystal‐derived permeability). Additionally, the CO2/N2 permeation selectivity for a representative membrane (23.9–28.6) moves toward that of single crystal (24.6–29.6). The unique structure and superior CO2/N2 separation performance make UiO‐66‐CN@sPIM‐1 membranes promising in practical CO2 separations.

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Membrane materials with excellent selectivity and high permeability are crucial to efficient membrane gas separation. Microporous organic materials have evolved as an alternative candidate for fabricating membranes due to their inherent attributes, such as permanent porosity, high surface area, and good processability. Herein, a unique pore-chemistry concept for the designed synthesis of microporous organic membranes, with an emphasis on the relationship between pore structures and membrane performances, is introduced. The latest advances in microporous organic materials for potential membrane application in gas separation of H , CO , O , and other industrially relevant gases are summarized. Representative examples of the recent progress in highly selective and permeable membranes are highlighted with some fundamental analyses from pore characteristics, followed by a brief perspective on future research directions.