All-inorganic CsPbX3 (X = Cl, Br or I) perovskite nanocrystals have attracted extensive interest recently due to their exceptional optoelectronic properties. In an effort to improve the charge separation and transfer following efficient exciton generation in such nanocrystals, novel functional nanocomposites were synthesized by the in situ growth of CsPbBr3 perovskite nanocrystals on two-dimensional MXene nanosheets. Efficient excited state charge transfer occurs between CsPbBr3 NCs and MXene nanosheets, as indicated by significant photoluminescence (PL) quenching and much shorter PL decay lifetimes compared with pure CsPbBr3 NCs. The as-obtained CsPbBr3/MXene nanocomposites demonstrated increased photocurrent generation in response to visible light and X-ray illumination, attesting to the potential application of these heterostructure nanocomposites for photoelectric detection. The efficient charge transfer also renders the CsPbBr3/MXene nanocomposite an active photocatalyst for the reduction of CO2 to CO and CH4. This work provides a guide for exploration of perovskite materials in next-generation optoelectronics, such as photoelectric detectors or photocatalyst.

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Different spatiotemporal modes of ionization wave propagation at opposite polarity of bipolar pulses in a micro-dielectric barrier discharge structure device are investigated. The device is fabricated on a heavily doped n-type silicon substrate, and a 1 cm × 1 cm square cavity is formed on the 180 μm-thick polyimide film. Different modes of ionization wave propagation determined by the polarity of bipolar pulses are observed, and the details of streamerlike mode and wavelike mode under positive and negative half cycles of pulses are investigated, respectively. The propagation speeds of streamerlike ionization waves and wavelike ionization waves are ∼120 km/s and ∼40 km/s on average and ∼150 km/s and ∼70 km/s in maximum, respectively. Different parameters of bipolar pulses, especially the rising time of pulses, are applied to the proposed device to explore the variation of ionization wave propagation properties. The results show that the modes of the ionization wave propagation are barely changed when the device is driven by different rising time pulses. However, the initial plasma generation time and propagation speed are greatly changed. With a decrease in the rising time from 400 ns to 50 ns, the initial plasma generation time is brought forward over 200 ns, and the ionization wave propagation speed is improved over 30% for both cases. The results imply great significance in the exploration of the dynamics of plasma discharge evolution and regulation of plasma discharge properties through manipulating the pulse parameters.

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Self-organization of periodic, streamer-like ionization waves in planar microplasma devices having a dielectric barrier discharge structure is observed. In contrast to plasma propagation in arrays of microchannels or microcavities, the ionization waves originate from a single point but rapidly sub-divide into as many as 10 'branch' plasma wave packets that eventually recombine. In less than 70 ns, the self-organization of the spatially-periodic array of co-propagating branches is complete and two successive sets of waves, separated in distance and time by ∼1.8 mm and ∼50 ns, respectively, are generated. The mean propagation velocity of each plasma packet is greater than 70 km s −1 but values as large as 150 km s −1 have been measured. Because the propagation path for all subsequent streamers is established by the first set of plasma packets, the intensity of the second set is noticeably enhanced. The average length of the primary branches is ∼1.5 mm but reaches a maximum of ∼4.5 mm as the wave packets travel an overall distance of 1 cm. These phenomena are interpreted in terms of photoelectron emission from the floor and walls of the shallow dielectric microcavity, induced by radiation from the advancing packets, and the rapid collapse of the sheath of each microplasma owing to the accumulation of charge on the underlying dielectric. The spatial profiles of the propagating plasmas suggest that generating and probing plasma solitons may now be feasible.