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Lithium iron phosphate battery packs are widely employed for energy storage in electrified vehicles and power grids. However, their flat voltage curves rendering the weakly observable state of charge are a critical stumbling block for charge equalization management. This paper focuses on realtime active balancing of series-connected lithium iron phosphate batteries. In the absence of accurate in-situ state information in the voltage plateau, a balancing current ratio (BCR) based algorithm is proposed for battery balancing. Then, BCR-based and voltage-based algorithms are fused, responsible for the balancing task within and beyond the voltage plateau, respectively. The balancing process is formulated as a batch-based run-to-run control problem, as the first time in the research area of battery management. The control algorithm acts in two timescales, including time-wise control within each batch run and batch-wise control at the end of each batch. Hardware-in-the-loop experiments demonstrate that the proposed balancing algorithm is able to release 97.1% of the theoretical capacity and can improve the capacity utilization by 5.7% from its benchmarking algorithm. Furthermore, the proposed algorithm can be coded in C language with the binary code in 118,328 bytes only and thus is readily implementable in real-time.
This paper develops a new prediction method for the aging trajectory of lithium-ion batteries with significantly reduced experimental tests. This method is driven by data collected from two types of battery operation modes. The first type is accelerated aging tests that are performed under stress factors, such as overcharging, over-discharging and large current rates, and cover most of the battery lifespan. In the second operation mode, the same kinds of cells are aged at normal speeds to generate a partial aging profile. An accelerated aging model is developed based on the first type of data and is then migrated as a new model to describe the normalspeed aging behavior. Under the framework of Bayesian Monte Carlo algorithms, the new model is parameterized based on the second type of data and is used for prediction of the remaining battery aging trajectory. The proposed prediction method is validated on three types of commercial batteries and also compared with two benchmark algorithms. The sensitivity of results to the number of cycles is investigated for both modes. Illustrative results demonstrate that based on the normal-speed aging data collected in the first 30 cycles, the proposed method can predict the entire aging trajectories (up to 500 cycles) at a root-mean-square error of less than 2.5% for all considered scenarios. When only using the first five-cycle data for model training, such a prediction error is bounded by 5% for aging trajectories of all the tested batteries.
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