The development of tin (Sn)‐based perovskite solar cells (PSCs) is hindered by their lower power conversion efficiency and poorer stability compared to the lead‐based ones, which arise from the easy oxidation of Sn2+ to Sn4+. Herein, phenylhydrazine hydrochloride (PHCl) is introduced into FASnI3 (FA = NH2CH NH2+) perovskite films to reduce the existing Sn4+ and prevent the further degradation of FASnI3, since PHCl has a reductive hydrazino group and a hydrophobic phenyl group. Consequently, the device achieves a record power conversion efficiency of 11.4% for lead‐free PSCs. Besides, the unencapsulated device displays almost no efficiency reduction in a glove box over 110 days and shows efficiency recovery after being exposed to air, due to a proposed self‐repairing trap state passivation process.
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Aims
Alzheimer's disease (AD) is a progressive neurodegenerative disorder. Previous studies have demonstrated abnormalities in functional connectivity (FC) of AD under the assumption that FC is stationary during scanning. However, studies on the FC dynamics of AD, which may provide more insightful perspectives in understanding the neural mechanisms of AD, remain largely unknown.
Methods
Combining the sliding‐window approach and the k‐means algorithm, we identified three reoccurring dynamic FC states from resting‐state fMRI data of 26 AD and 26 healthy controls. The between‐group differences both in FC states and in regional temporal variability were calculated, followed by a correlation analysis of these differences with cognitive performances of AD patients.
Results
We identified three reoccurring FC states and found abnormal FC mainly in the frontal and temporal cortices. The temporal properties of FC states were changed in AD as characterized by decreased dwell time in State I and increased dwell time in State II. Besides, we found decreased regional temporal variability mainly in the somatomotor, temporal and parietal regions. Disrupted dynamic FC was significantly correlated with cognitive performances of AD patients.
Conclusion
Our findings suggest abnormal dynamic FC in AD patients, which provides novel insights for understanding the pathophysiological mechanisms of AD.
In this paper, we theoretically and experimentally demonstrate broadband metamaterial absorbers that work in the mid-infrared regime. In the absorbers, two or four gold cross resonators with different sizes are multiplexed in a unit cell on SiO(2) spacing layer on top of gold ground plane. Compared with the single cross resonator absorbers with a Q factor of 6.39, the developed absorber with two cross resonators multiplexed reduces the Q factor to 3.78. When four different cross resonators are integrated, the Q factor drops to as low as 1.85, and the bandwidth almost covers the full mid-infrared regime from 3 μm to 5 μm with absorbance higher than 50%.
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