In this work, to maximize the unique attributes of reduced graphene oxide (RGO) for excellent microwave absorption, the ultralight RGO aerogels with improved dispersion and interface polarization performance were fabricated via a facile cation-assisted hydrothermal treatment process. The prepared RGO/paraffin composite exhibits excellent microwave absorption (MA) performance in a wideband frequency range of 8.0 ∼ 18.0 GHz with an ultralow absorbent content of 0.5 wt.%. Such performance is comparable with most previously reported results on RGO-based composites but required much higher absorbent content. The mechanisms for the enhancement of polarization relaxation loss and conductive loss were investigated in detail. This study provides a promising and facile method for preparing RGO-based excellent microwave absorption materials with ultra-low filler content, which is significant for designing efficient MA absorbers.
A type of nanomesoporous modified red mud (MRM) catalyst was prepared and utilized for catalytic methane decomposition (CMD) to produce hydrogen. The modification process significantly simplified the mineral composition of the red mud (RM); in the meantime, the physical and chemical structure of RM was changed. TEM images suggested that MRM was a kind of nanomesoporous material assembled by a number of uniformly nanoscale particles, BET results showed that the pore size distributions of MRM were ranged from 3 to 12 nm, and the specific surface area and total pore volumes of red mud improved from 8.00 m2/g and 0.08 cm3/g to 190.61 m2/g and 0.39 cm3/g, respectively. The catalytic performance of the catalysts has been tested at 800°C; the results showed that MRM exhibited much higher activity and stability than RM for CMD.
A modified red mud-(MRM-) supported Fe catalyst ( Fe/MRM) was prepared using the homogeneous precipitation method and applied to methane decomposition to produce hydrogen. The TEM and SEM-EDX results suggested that the particle sizes of the Fe/MRM catalysts were much smaller than that of raw red mud (RM), and the active metal Fe was evenly distributed over the catalyst structure. Moreover, BET results indicated that the surface areas and pore volumes of the catalysts were significantly improved, and the pore sizes of Fe/MRM were distributed from 5 to 12 nm, which is typical for a mesoporous material. The activities of those catalysts for the catalytic decomposition of methane were studied at atmospheric pressure at a moderate temperature of 650 ∘ C; the results showed that the Fe/MRM catalysts were more active than RM and MRM. The methane conversion curves of Fe/MRM catalysts exhibited similar variation tendencies (three-step) during the reaction despite different Fe contents, and the loading amount of Fe clearly affected the activity of the catalysts.
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