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The fabrication of a magnetic nanoporous carbon (MNPC) via one-step direct carbonization of Co-based metal-organic framework has been achieved without using any additional carbon precursors. The morphology, structure, and magnetic behavior of the as-prepared Co-MNPC were characterized by using the techniques of scanning electron microscopy, transmission electron microscopy, powder X-ray diffraction, Raman spectroscopy, N2 adsorption, and vibrating sample magnetometer. The Co-MNPC has a high specific surface area, large pore volume, and super paramagnetism. Its performance was evaluated by the magnetic solid-phase extraction of some neonicotinoid insecticides from water and fatmelon samples followed by high-performance liquid chromatographic analysis. The effects of the main experimental parameters that could affect the extraction efficiencies were investigated. The results demonstrated that the Co-MNPC had an excellent adsorption capability for the compounds.

A dispersive liquid-liquid microextraction based on solidification of floating organic droplet (DLLME-SFO) has been developed as a new approach for the extraction of trace copper in water and beverage samples followed by the determination with flame atomic absorption spectrometry. In the DLLME-SFO, 8-hydroxy quinoline, 1-dodecanol, and methanol were used as chelating agent, extraction solvent and dispersive solvent, respectively. The experimental parameters related to the DLLME-SFO such as the type and volume of the extraction and dispersive solvent, extraction time, sample volume, the concentration of chelating agent and salt addition were investigated and optimized. Under the optimum conditions, the enrichment factor for copper was 122. The method was linear in the range from 0.5 to 300 ng mL −1 of copper in the samples with a correlation coefficient (r) of 0.9996 and a limit of detection of 0.1 ng mL −1. The method was applied to the determination of copper in water and beverage samples. The recoveries for the spiked water and beverage samples at the copper concentration levels of 5.0 and 10.0 ng mL −1 were in the range between 92.0% and 108.0%. The relative standard deviations (RSD) varied from 3.0% to 5.6%.

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Capacitive deionization (CDI) provides a promising option to provide affordable freshwater with simultaneously storing energy, but its scale application is usually limited owing to the poor performance of conventional materials...

A rapid and sensitive method has been established for the determination of four carbamate pesticides (carbofuran, carbaryl, pirimicarb, and diethofencarb) in water samples by using dispersive liquid-liquid microextraction coupled with high-performance liquid chromatography-diode array detection. Parameters that affect the extraction efficiency, such as the kind and volume of the extraction and disperser solvent, extraction time, and salt addition, were investigated and optimized. Under the optimum conditions, the enrichment factors were in the range between 101 and 145. The linearity of the method was obtained in the range of 5-500 ng mL(-1) with the correlation coefficients (r) ranging from 0.9978 to 0.9997. The method detection limits were 0.4-1.0 ng mL(-1). The relative standard deviations varied from 4.7% to 6.5% (n = 5). The relative recoveries of the four carbamates from water samples at spiking levels of 5.0 and 20.0 ng mL(-1) were 84.0-92.0% and 86.5-94.0%, respectively. The proposed method has been successfully applied to the analysis of target carbamate residues in river, rain, well, and tap water samples with satisfactory results.

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