A closed-loop process to recover lithium carbonate from cathode scrap of lithium-ion battery (LIB) is developed. Lithium could be selectively leached into solution using formic acid while aluminum remained as the metallic form, and most of the other metals from the cathode scrap could be precipitated out. This phenomenon clearly demonstrates that formic acid can be used for lithium recovery from cathode scrap, as both leaching and separation reagent. By investigating the effects of different parameters including temperature, formic acid concentration, HO amount, and solid to liquid ratio, the leaching rate of Li can reach 99.93% with minor Al loss into the solution. Subsequently, the leaching kinetics was evaluated and the controlling step as well as the apparent activation energy could be determined. After further separation of the remaining Ni, Co, and Mn from the leachate, LiCO with the purity of 99.90% could be obtained. The final solution after lithium carbonate extraction can be further processed for sodium formate preparation, and Ni, Co, and Mn precipitates are ready for precursor preparation for cathode materials. As a result, the global recovery rates of Al, Li, Ni, Co, and Mn in this process were found to be 95.46%, 98.22%, 99.96%, 99.96%, and 99.95% respectively, achieving effective resources recycling from cathode scrap of spent LIB.
Water splitting is promising to realize a hydrogen‐based society. The practical use of molecular water‐splitting catalysts relies on their integration onto electrode materials. We describe herein the immobilization of cobalt corroles on carbon nanotubes (CNTs) by four strategies and compare the performance of the resulting hybrids for H2 and O2 evolution. Co corroles can be covalently attached to CNTs with short conjugated linkers (the hybrid is denoted as H1) or with long alkane chains (H2), or can be grafted to CNTs via strong π–π interactions (H3) or via simple adsorption (H4). An activity trend H1≫H3>H2≈H4 is obtained for H2 and O2 evolution, showing the critical role of electron transfer ability on electrocatalysis. Notably, H1 is the first Janus catalyst for both H2 and O2 evolution reactions in pH 0–14 aqueous solutions. Therefore, this work is significant to show potential uses of electrode materials with well‐designed molecular catalysts in electrocatalysis.
With the increasing
consumption of lithium ion batteries (LIBs)
in electric and electronic products, the recycling of spent LIBs has
drawn significant attention due to their high potential of environmental
impacts and waste of valuable resources. Among different types of
spent LIBs, the difficulties for recycling spent LiFePO4 batteries rest on their relatively low extraction efficiency and
recycling selectivity in which secondary waste is frequently generated.
In this research, mechanochemical activation was developed to selectively
recycle Fe and Li from cathode scrap of spent LiFePO4 batteries.
By mechanochemical activation pretreatment and the diluted H3PO4 leaching solution, the leaching efficiency of Fe and
Li can be significantly improved to be 97.67% and 94.29%, respectively.
To understand the Fe and Li extraction process and the mechanochemical
activation mechanisms, the effects of various parameters during Fe
and Li recovery were comprehensively investigated, including activation
time, cathode powder to additive mass ratio, acid concentration, the
liquid-to-solid ratio, and leaching time. Subsequently, the metal
ions after leaching can be recovered by selective precipitation. In
the whole process, about 93.05% Fe and 82.55% Li could be recovered
as FePO4·2H2O and Li3PO4, achieving selective recycling of metals for efficient use
of resources from spent lithium ion batteries.
Electronic structures of zigzag edged graphene nanoribbons (ZGNRs) doped with boron (B) or nitrogen (N) atoms are investigated by spin polarized first-principles calculations. We find that ZGNRs can be tuned to be either semiconducting, half-metallic, or metallic by controlling the distance of the impurity atoms to the edges. A new scheme is identified to achieve full half-metallicity in ZGNRs by doping B atom at one edge and N atom at the other. We find that the origin of the half-metallicity is due to interaction between the edge states and B/N atoms which results in direct control over the electron occupation of the edge states. This mechanism is so robust that full half-metallicity can always be produced in ZGNRs irrespective of the ribbon width, which opens new possibilities for applications of ZGNRs in spintronic devices.
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