Large-scale fabrication of superhydrophobic surfaces with excellent durability by simple techniques has been of considerable interest for its urgent practical application in oil-water separation in recent years. Herein, we proposed a facile vapor-liquid sol-gel approach to fabricating highly durable and robust superhydrophobic polydimethylsiloxane@silica surfaces on the cross-structure polyester textiles. Scanning electron microscopy and Fourier transform infrared spectroscopy demonstrated that the silica generated from the hydrolysis-condensation of tetraethyl orthosilicate (TEOS) gradually aggregated at microscale driven by the extreme nonpolar dihydroxyl-terminated polydimethylsiloxane (PDMS(OH)). This led to construction of hierarchical roughness and micronano structures of the superhydrophobic textile surface. The as-fabricated superhydrophobic textile possessed outstanding durability in deionized water, various solvents, strong acid/base solutions, and boiling/ice water. Remarkably, the polyester textile still retained great water repellency and even after ultrasonic treatment for 18 h, 96 laundering cycles, and 600 abrasion cycles, exhibiting excellent mechanical robustness. Importantly, the superhydrophobic polyester textile was further applied for oil-water separation as absorption materials and/or filter pipes, presenting high separation efficiency and great reusability. Our method to construct superhydrophobic textiles is simple but highly efficient; no special equipment, chemicals, or atmosphere is required. Additionally, no fluorinated slianes and organic solvents are involved, which is very beneficial for environment safety and protection. Our findings conceivably stand out as a new tool to fabricate organic-inorganic superhydrophobic surfaces with strong durability and robustness for practical applications in oil spill accidents and industrial sewage emission.
Body Area Networks (BANs) are expected to play a major role in patient health monitoring in the near future. Providing an efficient key agreement with the prosperities of plugn-play and transparency to support secure inter-sensor communications is critical especially during the stages of network initialization and reconfiguration. In this paper, we present a novel key agreement scheme termed Ordered-Physiological-Feature-based Key Agreement (OPFKA), which allows two sensors belonging to the same BAN to agree on a symmetric cryptographic key generated from the overlapping physiological signal features, thus avoiding the pre-distribution of keying materials among the sensors embedded in the same human body. The secret features computed from the same physiological signal at different parts of the body by different sensors exhibit some overlap but they are not completely identical. To overcome this challenge, we detail a computationally efficient protocol to securely transfer the secret features of one sensor to another such that two sensors can easily identify the overlapping ones. This protocol possesses many nice features such as the resistance against brute force attacks. Experimental results indicate that OPFKA is secure, efficient, and feasible. Compared with the state-of-the-art PSKA protocol, OPFKA achieves a higher level of security at a lower computational overhead.Index Terms-Body Area Networks (BANs); secure intersensor communications; Inter-Pulse-Interval (IPI); physiological feature based key agreement.
Body Area Networks (BANs) are expected to play a major role in the field of patient-health monitoring in the near future. While it is vital to support secure BAN access to address the obvious safety and privacy concerns, it is equally important to maintain the elasticity of such security measures. For example, elasticity is required to ensure that first-aid personnel have access to critical information stored in a BAN in emergent situations. The inherent tradeoff between security and elasticity calls for the design of novel security mechanisms for BANs.In this paper, we develop the Fuzzy Attribute-Based Signcryption (FABSC), a novel security mechanism that makes a proper tradeoff between security and elasticity. FABSC leverages fuzzy Attribute-based encryption to enable data encryption, access control, and digital signature for a patient's medical information in a BAN. It combines digital signatures and encryption, and provides confidentiality, authenticity, unforgeability, and collusion resistance. We theoretically prove that FABSC is efficient and feasible. We also analyze its security level in practical BANs.
Superhydrophobic surfaces with tunable adhesion from lotus-leaf to rose-petal states have generated much attention for their potential applications in self-cleaning, anti-icing, oil-water separation, microdroplet transportation, and microfluidic devices. Herein we report a facile magnetic-field-manipulation strategy to fabricate dual-functional superhydrophobic textiles with asymmetric roll-down/pinned states on the two surfaces of the textile simultaneously. Upon exposure to a static magnetic field, fluoroalkylsilane-modified iron oxide (F-FeO) nanoparticles in polydimethylsiloxane (PDMS) moved along the magnetic field to construct discrepant hierarchical structures and roughnesses on the two sides of the textile. The positive surface (closer to the magnet, or P-surface) showed a water contact angle up to 165°, and the opposite surface (or O-surface) had a water contact angle of 152.5°. The P-surface where water droplets easily slid off with a sliding angle of 7.5° appeared in the "roll-down" state as Cassie mode, while the O-surface was in the "pinned" state as Wenzel mode, where water droplets firmly adhered even at vertical (90°) and inverted (180°) angles. The surface morphology and wetting mode were adjustable by varying the ratios of F-FeO nanoparticles and PDMS. By taking advantage of the asymmetric adhesion behaviors, the as-fabricated superhydrophobic textile was successfully applied in no-loss microdroplet transportation and oil-water separation. Our method is simple and cost-effective. The fabricated textile has the characteristics of superhydrophobicity, magnetic responsiveness, excellent chemical stability, adjustable surface morphology, and controllable adhesion. Our findings conceivably stand out as a new tool to fabricate functional superhydrophobic materials with asymmetric surface properties for various potential applications.
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