A novel sodium lignosulphonate (SLS)-polyvinyl alcohol (PVA) spherical macroporous bioadsorbent (SLSP) was synthesized by reversed phase suspension polymerization. Comparing with powdery and high water solubility SLS, this new spherical bioadsorbent exhibited relative stability under static force. SEM and FTIR proved the cross-linking of SLS and PVA. TG curves of SLS and SLSP indicated that the thermal property of SLS had been improved by cross-linking modification. Meanwhile, comprehensive adsorption study of Pb (II) on this bioadsorbent was conducted regarding the effects of time, initial PH and initial Pb (II) concentration. 90% of Pb (II) from aqueous solution could be removed by 0.4g of the adsorbent at 25°C for less than 3h. The adsorption process was determined to be consistent with the Langmuir isotherm.
This paper reports the feasibility of using rice husk to remove Ag+ from synthetic wastewater. Effect of various adsorption parameters, namely, pH, adsorbent dose, initial silver concentration and contact time has been studied in batch systems. The results indicated that rice husk offered high removal efficiency, fast adsorption rate and high uptake capacity for Ag+ ions. The equilibrium was attained within 20 min and the maximum removal efficiency at 11g/L rice husk and at pH 2 was found to be 99.76%. The kinetic data was fitted well to pseudo-second order model. The isotherm adsorption data was well described by the Langmuir isotherm model and the maximum uptake capacity of Ag+ ions onto rice husk was found to be 42.43 mg/g.
A series of Ba-Al-O/NSR supports were prepared by co-precipitation in this work. The effect of Al/Ba atomic ratio and calcination temperature on the structure and texture of the supports was investigated carefully. The XRD spectra show that Ba is mainly exist in the form of BaAl2O4, and Al exists in Al2O3. The results of SBET indicate that the supports possess relative high specific surface area (70~150 m2/g). The effect of different parameters on the process of supports synthesized was investigated carefully. The results show that the structure and specific surface area of support is significantly depended on calcination temperature.
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