Three novel thiocyanato-bridged polynuclear cadmium(II) complexes, [Cd(HL1)(NCS) 2 (μ 1,3 -NCS)] n (1), [CdL2(μ 1,3 -NCS) 2 ] n (2),, have been synthesized and structurally characterized by elemental analysis, IR spectra and single-crystal X-ray diffraction.Each cadmium(II) atom in the complexes is in an octahedral coordination. The urease inhibitory activities of the complexes were evaluated. All of them showed potent inhibitions against jack bean urease.
Secondary caries seriously limits the lifetime of composite resin. However, integrating all desirable properties (i.e., mechanical, antibacterial, bioactivity, and biocompatibility) into one composite resin is still challenging. Herein, a novel bioactive glass (BAG)-modified hybrid composite resin has been successfully developed to simultaneously achieve excellent mechanical properties, good biocompatibility, and antibacterial and remineralizing capabilities. When the mass fractions of BAG particles were added from 8 to 23 wt %, the original mechanical properties of the composite resin, including flexural strength and compressive strength, were not obviously affected without compromising the degree of conversion. Although the BAG incorporation of mass fractions of 16 wt % to 23 wt % in composite resins reduced cell viability, the viability could be recovered to normal by adjusting the pH value. Moreover, the BAG-modified composite resins that were obtained showed good antibacterial effects against Streptococcus mutans and enhanced remineralizing activity on demineralized dentin surfaces with increasing incorporation of BAG particles. The possible mechanisms for antibacterial and remineralizing activity might be closely related to the release of bioactive ions (Ca2+, Si4+), suggesting that its antibacterial and biological properties can be controlled by modulating the amounts of bioactive ions. The capability to balance the mechanical properties, cytotoxicity, antibacterial activity, and bioactivity makes the BAG-modified composite resin a promising prospect for clinical application. Our findings provide insight into better design and intelligent fabrication of bioactive composite resins.
Facing the existing digital image libraries on landscape, researchers need to urgently solve a challenging problem: how to realize rational management and accurate retrieval of landscape images that contain feature information like hierarchy, layout, color system, and color matching. For accurate organization and labeling of landscape Images, this paper presents a novel method for feature extraction and image retrieval of landscape images based on image processing. Firstly, a color quantization process was designed for landscape images, and used to analyze the color composition and color space pattern (CSP) of such images. Next, the existing methods, which are suitable for the extraction of color features from landscape Images, were briefly reviewed, and the basic flows of our improved algorithm and division method of landscape color blocks (LCBs) were explained. Finally, the retrieval performance of landscape images was improved by matching of weighted color blocks of regional landscape, based on the multi-dimensional color eigenvectors of landscape image. The experimental results demonstrate the effectiveness of our algorithm. The research results shed light on the feature extraction from other types of color images.
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