Cross-linking is known to play a pivotal role in the relaxation dynamics and mechanical properties of thermoset polymers, which are commonly used in structural applications because of their light weight and inherently strong nature. Here, we employ a coarse-grained (CG) polymer model to systematically explore the effect of cross-link density on basic thermodynamic properties as well as corresponding changes in the segmental dynamics and elastic properties of these network materials upon approaching their glass transition temperatures ( Tg). Increasing the cross-link density unsurprisingly leads to a significant slowing down of the segmental dynamics, and the fragility K of glass formation shifts in lockstep with Tg, as often found in linear polymer melts when the polymer mass is varied. As a consequence, the segmental relaxation time τα becomes almost a universal function of reduced temperature, ( T − Tg)/ Tg, a phenomenon that underlies the applicability of the “universal” Williams–Landel–Ferry (WLF) relation to many polymer materials. We also test a mathematical model of the temperature dependence of the linear elastic moduli based on a simple rigidity percolation theory and quantify the fluctuations in the local stiffness of the network material. The moduli and distribution of the local stiffness likewise exhibit a universal scaling behavior for materials having different cross-link densities but fixed ( T − Tg)/ Tg. Evidently, Tg dominates both τα and the mechanical properties of our model cross-linked polymer materials. Our work provides physical insights into how the cross-link density affects glass formation, aiding in the design of cross-linked thermosets and other structurally complex glass-forming materials.
To develop structure–property relationships for cross-linked thermosetting polymers, it is crucial to better understand key factors that control their segmental dynamics and macroscopic properties. Here, we employ a coarse-grained (CG) polymer model to systematically explore the combined effect of varying the cohesive energy (ε) and cross-link density (c) on the segmental relaxation time and mechanical properties for a model cross-linked glass-forming thermoset material. We find that increasing c increases both the glass transition temperature T g and fragility of glass formation, while the fragility decreases with an increase in ε. These competing effects of ε and c on fragility are practically important since fragility determines the overall temperature width of the glass formation over which the non-Arrhenius temperature dependence is observed. Our simulation results show that the basic mechanical properties (i.e., bulk and shear moduli) of cross-linked thermosets are mainly influenced by ε. More interestingly, the macroscopic mechanical properties are found to be strongly correlated with the Debye–Waller parameter ⟨u 2⟩, a measure of material “stiffness” at a molecular level. In particular, the distribution of local molecular stiffness, 1/⟨u 2⟩, exhibits a nearly universal Gaussian distribution at a fixed reduced temperature T/T g. Our work reveals the key and competitive roles of cohesive energy and cross-link density in controlling the segmental dynamics, large scale, and local mechanical properties of cross-linked thermosets, providing an understanding that should be useful in the molecular design of these materials.
Beta gallium oxide (β-GaO) is an emerging ultrawide band gap (4.5 eV-4.9 eV) semiconductor with attractive properties for future power electronics, optoelectronics, and sensors for detecting gases and ultraviolet radiation. β-GaO thin films made by various methods are being actively studied toward such devices. Here, we report on the experimental demonstration of single-crystal β-GaO nanomechanical resonators using β-GaO nanoflakes grown via low-pressure chemical vapor deposition (LPCVD). By investigating β-GaO circular drumhead structures, we demonstrate multimode nanoresonators up to the sixth mode in high and very high frequency (HF/VHF) bands, and also realize spatial mapping and visualization of the multimode motion. These measurements reveal a Young's modulus of E = 261 GPa and anisotropic biaxial built-in tension of 37.5 MPa and 107.5 MPa. We find that thermal annealing can considerably improve the resonance characteristics, including ∼40% upshift in frequency and ∼90% enhancement in quality (Q) factor. This study lays a foundation for future exploration and development of mechanically coupled and tunable β-GaO electronic, optoelectronic, and physical sensing devices.
Using molecular dynamics simulations, disorder trapping associated with solidification is studied for the (100), (110), and (111) growth directions in the B2 NiAl ordered alloy compound. At the high interface velocities studied we observe pronounced disorder and defect trapping, i.e., the formation of antisite defects and vacancies in the crystal at higher than equilibrium concentrations upon rapid solidification. The vacancies are located primarily on the Ni sublattice and the majority of antisite defects are Ni atoms on the Al sublattice, while the concentration of Al on the Ni sublattice is negligibly small. The defect concentration is found to increase in an approximately linear relationship with increasing the interface velocity. Further there is no significant anisotropy in the defect concentrations for different interface orientations. Our results suggest that the currently available models of disorder trapping should be extended to include both antisite defects and vacancies.
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