In an effort to effectively control coal dust pollution and thereby reduce the harm of coal dust to human health, we prepared a highly efficient composite dust suppressant. First, dynamic contact angle and zeta potential measurements were used to select sodium dodecyl sulfonate (SDS) over sodium carboxymethyl cellulose and trisodium methyl silicon as the complementary additive to soy protein isolate for the dust suppressant. We employed viscosity and wind erosion resistance tests to compare the performance of the composite dust suppressant with three common, commercially available suppressants. As the concentration of the composite dust suppressant was increased, the viscosity increased, reaching a maximum value of 22.7 mPa·s at a concentration of 5 wt%. The 5 wt% concentration of the composite dust suppressant provided the lowest wind erosion rate (20.62%) at a wind speed of 12 m/s. The composite dust suppressant also had good bonding performance and wind erosion resistance. Scanning electron microscopy, X-ray diffraction, and thermogravimetric analysis were used to characterize the properties of the dust suppressants. The dust suppressant, which had a crystal-like structure, could easily capture coal dust and form an effective package. In addition, the density of the dust suppressant film increased as its crystallinity increased. The increased density was beneficial in that it enabled the dust suppressant to form a hard, solidified shell on the surface of coal dust, which improved dust suppression. The composite dust suppressant also had good thermal stability.
In this study, an experimental investigation was presented on the oxidation behaviors of bituminous coal for different inert gases (N2 and CO2) at different concentrations (oxygen concentration indexes 21%, 18.4%, 15.8%, and 13.1%) using a temperature-programmed experimental device. The purpose of this research was to examine the oxidation patterns of bituminous coal under different inert conditions. The results showed that (1) the oxidative heating of the coal underwent two stages: an initial slow heating stage and a fast heating stage. The injection of both inert gases would result in a delay in the crossing point temperature (CPT) of the coal, but injection of N2 resulted in greater delays in the CPT of the coal; (2) the injection of both N2 and CO2 inhibited the concentrations of CO and alkane/olefin gases produced from the oxidative heating of the coal, with CO2 displaying higher inhibition efficiencies than that of N2. (3) under non-inerting environment, the C2H4 and C2H6 generation temperatures were 110°C and 100°C. Under inerting environment, when N2 was injected, the higher the N2 concentration, the higher the initial C2H4 and C2H6 generation temperatures; when CO2 was injected, the higher the CO2 concentration, the lower the initial C2H4 and C2H6 generation temperatures. The above research results can be used to predict the spontaneous combustion of residual coal in an inert environment and prevent fires.
Aiming at the shortcomings of the current rock-breaking technology, a new type of high-energy expansion agent for energetic materials based on combustion-to-detonation was developed. By characterizing the basic physical and chemical properties of the high-energy expansion agent (HEEA) such as morphology, particle size distribution, and pyrolysis characteristics, the work performance of different types of high-energy expansion agents was analyzed in combination with the energy characteristics. The results showed that the relationship between the expansion work done by the gas to the outside world was WHEEA-I > WHEEA-II > WHEEA-III under the same quality of HEEA combustion. The damage effect of high-temperature and high-pressure gas cracking specimens generated by deflagration of HEEA was obvious, having the rule that the disturbance damage of rock caused by low heat and high gas specific volume was smaller, and the damage degree of rock caused by high heat and low gas specific volume was larger. The mechanism of HEEA combustion and detonation in confined space is revealed, which provides a theoretical basis for the application of HEEA-cracked rock.
The spatial accessibility of urban park green space (UPGS) plays a crucial role in promoting the healthy development of cities and their residents. However, previous studies have overestimated the accessibility of UPGS and failed to adequately consider the impact of variegated parks on residents’ needs. To fill this gap in the research, we first propose an improved two-step floating catchment area (Huff-2SFCA) method that takes into consideration the trade-offs between supply, demand, and walking time to calculate the UPGS accessibility index for the built-up area of Mianyang, China. Next, we assess the spatial characteristics of UPGS accessibility from both partial and overall points of view and further explore the relationship between accessibility and population size. Our results show that (1) every street area has a different form of UPGS construction, and most of these spaces are of poor quality; (2) municipal-level parks are significantly more accessible than district-level parks, community-level parks, or neighborhood-level parks; (3) the overall distribution of accessibility is generally characterized by a decreasing trend along both sides of the river, with poor overall accessibility; and (4) 243 residential districts are located in high-demand–low-supply areas that need improving. This study can be employed to identify areas that are underserved by UPGS and can provide a basis for improving the accessibility of UPGS and promoting its health benefits.
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