Flexible chemical sensors usually require transfer of prepared layers or whole device onto special flexible substrates and further attachment to target objects, limiting the practical applications. Herein, a sprayed gas sensor array utilizing silver nanoparticles (AgNPs)-all-carbon hybrid nanostructures is introduced to enable direct device preparation on various target objects. The fully flexible device is formed using metallic single-walled carbon nanotubes as conductive electrodes and AgNPs-decorated reduced graphene oxide as sensing layers. The sensor presents sensitive response ( R/ R) of 6.0-20 ppm NO, great mechanical robustness (3000 bending cycles), and obvious sensing ability as low as 0.2 ppm NO at room temperature. The sensitivity is about 3.3 and 13 times as that of the sample based on metal electrodes and the sample without AgNP decoration. The fabrication method demonstrates good scalability and suitability on the planar and nonplanar supports. The devices attached on a lab coat or the human body perform stable performance, indicating practicability in wearable and portable fields. The flexible and scalable sensor provides a new choice for real-time monitoring of toxic gases in personal mobile electronics and human-machine interactions.
In
this work, we report on UV illumination-enhanced room-temperature
trace NH3 detection based on ternary composites of reduced
graphene oxide nanosheets (rGO), titanium dioxide nanoparticles (TiO2), and Au nanoparticles as the sensing layer, which is the
first reported so far. The effect of the UV state as well as componential
combination and content on the sensing behavior disclosed that rGO
nanosheets served not only as a template to attach TiO2 and Au but also as an effective electron collector and transporter,
TiO2 nanoparticles acted as a dual UV and NH3 sensitive material, and Au nanoparticles could increase the sorption
sites and promote charge separation of photoinduced electron–hole
pairs. The as-prepared rGO/TiO2/Au sensors were endowed
with a sensing response of 8.9% toward 2 ppm of NH3, a
sensitivity of 1.43 × 10–2/ppm within the investigated
range, nice selectivity, robust operation repeatability, and stability,
which was fairly competitive in comparison with previous work. Meanwhile,
the experimental results provided clear evidence of inspiring UV-enhanced
gas detection catering for the future demand of low power-consumption
and high sensitivity.
A facile one-step solution method has been developed here to fabricate hierarchical ZnO nanosheet-nanorod architectures for compositing with poly(3-hexylthiophene) (P3HT) for fabricating a hybrid NO2 sensor. The hierarchical ZnO nanosheet-nanorod architectures were controllably synthesized by aging the solutions containing 0.05 mol·L(-1) Zn(2+) and 0.33 mol·L(-1) OH(-) at 60 °C through a metastable phase-directed mechanism. The concentration of OH(-) played a huge role on the morphology evolution. When the [OH(-)] concentration was decreased from 0.5 to 0.3 mol·L(-1), the morphology of the ZnO nanostructures changed gradually from monodispersed nanorods (NR) to nanorod assemblies (NRA), and then to nanosheet-nanorod architectures (NS-NR) and nanosheet assemblies (NSA), depending on the formation of various metastable, intermediate phases. The formation of NS-NR included the initial formation of ZnO nanosheets/γ-Zn(OH)2 mixed intermediates, followed by the dissolution of Zn(OH)2, which served as soluble zinc source. Soluble Zn(OH)2 facilitated the dislocation-driven secondary growth of ZnO nanorod arrays on the primary defect-rich nanosheet substrates. Hybrid sensors based on composite films composed of P3HT and the as-prepared ZnO nanostructures were fabricated for the detection of NO2 at room temperature. The P3HT/ZnO NS-NR bilayer film exhibited not only the highest sensitivity but also good reproducibility and selectivity to NO2 at room temperature. The enhanced sensing performance was attributed to the formation of the P3HT/ZnO heterojunction in addition to the enhanced adsorption of NO2 by NS-NR ZnO rich in oxygen-vacancy defects.
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