The polarization force between an electrically charged atomic force microscope tip and a substrate has been used to follow the processes of condensation and evaporation of a monolayer of water on mica at room temperature. Condensation proceeds in two distinct structural phases. Up to about 25 percent humidity, the water film grows by forming two-dimensional clusters of less than a few 1000 angstroms in diameter. Above about 25 percent humidity, a second phase grows, forming large two-dimensional islands with geometrical shapes in epitaxial relation with the underlaying mica lattice. The growth of this second water phase is completed when the humidity reaches about 45 percent. The reverse process of evaporation has also been imaged.

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Nonlinear optical techniques (second-harmonic and sum-frequency generation) have been used to study the structure of organic molecules that are confined and compressed between a lens and a flat surface. The molecules studied include self-assembled monolayers of n-octadecyltriethoxysilane and Langmuir-Blodgett films of stearic acid, octadecylalcohol, octadecylamine, and a liquid-crystal molecule 4'-n-octyl-4-cyanobiphenyl (8CB). The contact area created by elastic deformation of the flat surface and lens under pressure was large enough to contain the entire laser beam (& 100 pm radius at = 10 MPa for R =15 cm). Under these conditions, the sum-frequency generation (from CH3 and OH stretch modes) and second-harmonic generation (8CB) signals were found to decrease by a factor between 100 and 1000 times the original signal. This indicates vanishing of the second-order monolayer susceptibility due to disorder of the head groups and/or flattening of the molecular axis so that they lie parallel to the surface. The phenomenon was reversible and the nonlinear signals recovered completely upon removal of the pressure.

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Software architectural design has an enormous effect on downstream software artifacts. Decomposition of function for the final system is one of the critical steps in software architectural design. The process of decomposition is typically conducted by designers based on their intuition and past experiences, which may not be robust sometimes. This paper presents a study of applying the clustering technique to support system decomposition based on requirements and their attributes. The approach can support the architectural design process by grouping closely related requirements to form a subsystem or module. In this paper, we demonstrate our experiments in applying the approach to an industrial communication protocol software system and comparing several clustering algorithms. The result obtained from WPGMA (weighted pair-group method using arithmetic averages) shows closer resemblance than other clustering methods to the one developed by the designer.

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