This paper introduces and describes the radio and plasma wave investigation on the STEREO Mission: STEREO/WAVES or S/WAVES. The S/WAVES instrument includes a suite of state-of-the-art experiments that provide comprehensive measurements of the three components of the fluctuating electric field from a fraction of a hertz up to 16 MHz, plus a single frequency channel near 30 MHz. The instrument has a direction finding or goniopolarimetry capability to perform 3D localization and tracking of radio emissions associated with streams of energetic electrons and shock waves associated with Coronal Mass Ejections (CMEs). The scientific objectives include: (i) remote observation and measurement of radio waves excited by energetic particles throughout the 3D heliosphere that are associated with the CMEs and with solar flare phenomena, and (ii) in-situ measurement of the properties of CMEs and interplanetary shocks, such as their electron density and temperature and the associated plasma waves near 1 Astronomical Unit (AU). Two companion papers provide details on specific aspects of the S/WAVES instrument, namely the electric antenna system (Bale et al., Space Sci. Rev., 2007) and the direction finding technique (Cecconi et al., Space Sci. Rev., 2007).

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We have developed a line-by-line Atmospheric Radiative Transfer for Titan code that includes the most recent laboratory spectroscopic data and haze descriptions relative to Titan's stratosphere. We use this code to model Cassini Composite Infrared Spectrometer data taken during the numerous Titan flybys from 2006 to 2012 at surface-intercepting geometry in the 600-1500 cm −1 range for latitudes from 50 • S to 50 • N. We report variations in temperature and chemical composition in the stratosphere during the Cassini mission, before and after the Northern Spring Equinox (NSE). We find indication for a weakening of the temperature gradient with warming of the stratosphere and cooling of the lower mesosphere. In addition, we infer precise concentrations for the trace gases and their main isotopologues and find that the chemical composition in Titan's stratosphere varies significantly with latitude during the 6 years investigated here, with increased mixing ratios toward the northern latitudes. In particular, we monitor and quantify the amplitude of a maximum enhancement of several gases observed at northern latitudes up to 50 • N around mid-2009, at the time of the NSE. We find that this rise is followed by a rapid decrease in chemical inventory in 2010 probably due to a weakening north polar vortex with reduced lateral mixing across the vortex boundary.

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