We report on the synthesis of carbon nanotubes (CNTs) by direct thermal decomposition of ferrocene (Fe(C5H5)2). Our studies indicate that presence of a small amount of sulfur along with the ferrocene in the decomposition process strongly affects the quality of the CNTs produced and is crucial for obtaining thin diameter nanotubes. Raman spectroscopic investigations suggest that the atomic ratio of sulfur to the total iron plus sulfur content of approximately 0.09 yields CNTs with highly crystalline structure having diameters ranging from 0.85 nm to 1.75 nm. Electrochemical double layer capacitor electrodes fabricated from these CNTs show impressive energy storage properties, capable of delivering a maximum power density of approximately 27 KW/kg and energy density of approximately 2.12 Wh/Kg.
This paper reports the light emission from aligned multiwalled carbon nanotubes (MWNTs) under continuous wave CO(2) laser (λ = 10.6 µm) irradiation. Results indicate that the light emission is dependent on the angle θ between the laser incident direction and the nanotube axis. The relative intensity of the light emission at certain wavelengths shows a Lorentzian feature when θ varies from 0° to 90°. The Lorentzian fitting curve displays a distinct tendency between shorter (λ<600 nm) and longer wavelength (λ>700 nm). A minimum intensity was observed at θ(m) close to 67° under shorter wavelength, whereas a maximum intensity was shown at θ(m) of about 60° at longer wavelength. These results show the anisotropic property of aligned MWNTs.
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