Chemically converted graphene aerogels with ultralight density and high compressibility are prepared by diamine-mediated functionalization and assembly, followed by microwave irradiation. The resulting graphene aerogels with density as low as 3 mg cm(-3) show excellent resilience and can completely recover after more than 90% compression. The ultralight graphene aerogels possessing high elasticity are promising as compliant and energy-absorbing materials.
The idea of extending functions of graphene aerogels and achieving specific applications has aroused wide attention recently. A solution to this challenge is the formation of a hybrid structure where the graphene aerogels are decorated with other functional nanostructures. An infiltration-evaporation-curing strategy has been proposed by the formation of hybrid structure containing poly(dimethylsiloxane) (PDMS) and compressible graphene aerogel (CGA), where the cellular walls of the CGA are coated uniformly with an integrated polymer layer. The resulting composite shows enhanced compressive strength and a stable Young's modulus that are superior to those of pure CGAs. This unique structure combines the advantages of both components, giving rise to an excellent electromechanical performance, where the bulk resistance repeatedly shows a synchronous and linear response to variation of the volume during compression at a wide range of compressed rates. Furthermore, the foamlike structure delivers a water droplet with "sticky" superhydrophobicity and a size as large as 32 μL that remains tightly pinned to the composite, even when it is turned upside-down. This is the first demonstration of superhydrophobicity with strong adhesion on a foamlike structure. These outstanding properties qualify the PDMS/CGA composites developed here as promising candidates for a wide range of applications such as in sensors, actuators, and materials used for biochemical separation and tissue engineering.
A highly atom-economic procedure for the preparation of reduced graphene oxide/Mn3O4 (rGO/Mn3O4) composites is reported. Pristine graphene oxide/manganese sulfate (GO/MnSO4) suspension produced by modified Hummers method is utilized with high efficiency, which has been in situ converted into GO/Mn3O4 hybrid composite by air oxidation, then into rGO/Mn3O4 composite by means of dielectric barrier discharge (DBD) plasma-assisted deoxygenation. The Mn3O4 content of the rGO/Mn3O4 composites can be readily tailored. It is observed that Mn3O4 nanoparticles of 15-24 nm are well-dispersed on graphene sheets with Mn3O4 loading as high as 90%. The specific capacitance of the as-prepared rGO/Mn3O4 hybrids with 90% Mn3O4 reaches 193 F g(-1) when employed as the electrode material in neutral Na2SO4 electrolyte solutions (76 F g(-1) for pristine graphene and 95 F g(-1) for pure Mn3O4), which indicates the positive synergetic effects from both graphene and attached Mn3O4. The method developed in this study should offer a new technique for the large scale and highly atom-economic production of graphene/MnOx composites for many applications.
Multiresponsive hydrogels capable of reversible transitions to solutions upon changes in light, heat, shear and pH were prepared from low molecular weight azobenzene hydrogelators.
Nitrogen-doped graphene nanoribbon aerogels (N-GNRAs) are fabricated through the self-assembly of graphene oxide nanoribbons (GONRs) combined with a thermal annealing process. Amino-groups are grafted to the surface of graphene nanoribbons (GNRs) by an epoxy ring-opening reaction. High nitrogen doping level (7.6 atm% as confirmed by elemental analysis) is achieved during thermal treatment resulting from functionalization and the rich edge structures of GNRs. The three dimensional (3D) N-GNRAs feature a hierarchical porous structure. The quasi-one dimensional (1D) GNRs act as the building blocks for the construction of fishnet-like GNR sheets, which further create 3D frameworks with micrometer-scale pores. The edge effect of GNRs combined with nitrogen doping and porosity give rise to good electrical conductivity, superhydrophilic, highly compressible and low density GNRAs. As a result, a high capacity of 910 mA h g(-1) is achieved at a current density of 0.5 A g(-1) when they are tested as anode materials for lithium ion batteries. Further cell culture experiments with the GNRAs as human medulloblastoma DAOY cell scaffolds demonstrate their good biocompatibility, inferring potential applications in the biomedical field.
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