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In this research, the use of the sand capping technique for controlling phosphorus release from lake sediment was evaluated experimentally. Multiple acrylic columns were prepared to measure the dissolved oxygen, oxidation reduction potential, total phosphorus, and phosphate concentrations of the overlying water on the capping layer with thicknesses of 0, 40, and 80 mm. Sand capping effectively slowed down the reactions that depleted the dissolved oxygen, which as a result, controlled the total phosphorus release from the sediment. Oxidation reduction potential of overlying water was estimated by measuring dissolved oxygen in situ or vice versa by an empirical model proposed in this research. Sediment disturbance should be considered during field construction of the cap system. The experimental results showed that phosphorus existed in a more stable form with capping than without capping.

This research investigated the role of the pH buffer capacity of sediment on the dechlorination of atrazine using zero valent iron (ZVI). The buffer capacity of the sediment was quantified by batch experiments and estimated to be 5.0 cmol OH(-) . pH(-1). The sediments were spiked with atrazine at 7.25-36.23 mg kg(-1) (6.21 x 10(-7)-3.09 x 10(-6) mol atrazine . g(-1) sediment) for the batch experiments. The buffer capacity of the sediment maintained the sediment suspension at neutral pH, thereby enabling continuous dechlorination until the buffer capacity of the sediment was depleted. The pseudo-first order dechlorination constants were estimated to be in the range of 1.19 x 10(-2)-7.04 x 10(-2) d(-1) for the atrazine-spiked sediments.

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The tributary water quality and flowrate monitoring result, which is fundamental data for the establishment of the water environmental policy, is used as very important data for the implementation of TMDL. This study introduced how to use the tributary water quality and flowrate monitoring data for the analysis of the watersheds, the satisfactory assessment of water quality standards in the watersheds, the selection of watersheds for the establishment of the implementation plan, and the selection of the tributary catchments for improving the water quality using a stream grouping method. According to the analytical results of tributary catchment using water quality and flowrate monitoring data of thirty-seven tributaries in the Geum-River watershed at Chungcheongnam-do, the value of flowrate in the tributaries, which is located in the middle-lower Geum-River watershed, was greater than the other areas and the concentration of the water pollutants regardless of water quality parameters in the tributaries at Nonsancheon catchment was relatively higher than the other areas. The problems, which have the determination of satisfaction of water quality standards and selection of target watersheds for establishment of the implementation plan regardless of the water quality of tributary in the watershed due to the water quality and flowrate monitoring results of the main river, were improved use of the results of tributary water quality and flowrate monitoring. Also, the tributary catchments for improving the water quality, according to stream grouping method based on the results of tributary water quality and flowrate monitoring, were selected. In the Geum-River watershed at Chungcheongnam-do, the tributary in the Nonsancheon, Byeongcheoncheon, Seokseongcheon, Jocheon catchments, which has a large flow and a high concentration of water pollutants, should be preferentially selected for improving the water quality of the tributary in accordance with the reduction of the source of pollution.