We measure isotope shifts for five Yb þ isotopes with zero nuclear spin on two narrow optical quadrupole transitions 2 S 1=2 → 2 D 3=2 , 2 S 1=2 → 2 D 5=2 with an accuracy of ∼300 Hz. The corresponding King plot shows a 3 × 10 −7 deviation from linearity at the 3σ uncertainty level. Such a nonlinearity can indicate physics beyond the Standard Model (SM) in the form of a new bosonic force carrier, or arise from higherorder nuclear effects within the SM. We identify the quadratic field shift as a possible nuclear contributor to the nonlinearity at the observed scale, and show how the nonlinearity pattern can be used in future, more accurate measurements to separate a new-boson signal from nuclear effects.

We present a general analytical theory that enables one to determine accurately the unknown tip-sample interactions from the experimental measurement of the amplitude and phase of the oscillating tip in amplitude-modulation atomic force microscopy (AM-AFM). We apply the method to the known Lennard-Jones-type forces and find excellent agreement with the reconstructed results. AM-AFM, widely used in air and liquid, is now not only an imaging tool but also a quantitative force measurement tool.

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Since it was invented by Binnig et al in 1986, atomic force microscopy (AFM) has played a crucial role in nano-scale science and technology. AFM is a microscopic technique imaging a surface topography by using attractive and repulsive interaction forces between a few atoms attached at a tip on a cantilever and a sample. In the case of attractive forces, there are three main contributions causing AFM. These are short-range chemical force, van der Waals force and electrostatic force. As the effective ranges of these forces are different, one of them is dominant depending on distance. Atomic force spectroscopy is the force-versus-distance measurement when using AFM. The atomic force can be detected by cantilever bending caused by a tip-sample interacting force, which is called static AFM. Also, the atomic force can be detected by using the resonant properties of a cantilever, which is called dynamic AFM. Under the on-resonance condition, the frequency, amplitude or phase of the cantilever will be shifted by the interaction force. While the force can be estimated in static AFM, for dynamic AFM it requires complicated formalism to evaluate the force from measured amplitude, phase or frequency data. Recently developed techniques for ultra-high resolution imaging unveil sub-atomic features of the sample, which are facilitated by low temperature, ultra-high vacuum environments together with a stiff cantilever. In this study, progress related to theoretical and experimental imaging and force spectroscopy will be discussed.

We present a comprehensive study of the optical characteristics of Al x Ga 1Ϫx N epilayers (0рxр0.6) by means of photoluminescence ͑PL͒, PL excitation, and time-resolved PL spectroscopy. For Al x Ga 1Ϫx N with large Al content, we observed an anomalous PL temperature dependence: ͑i͒ an ''S-shaped'' PL peak energy shift ͑decrease-increase-decrease͒ and ͑ii͒ an ''inverted S-shaped'' spectral width broadening ͑increasedecrease-increase͒ with increasing temperature. We observed that the thermal decrease in integrated PL intensity was suppressed and the effective lifetime was enhanced in the temperature region showing the anomalous temperature-induced emission behavior, reflecting superior luminescence efficiency by suppressing nonradiative processes. All these features were enhanced as the Al mole fraction was increased. From these results, the anomalous temperature-induced emission shift is attributed to energy tail states due to alloy potential inhomogeneities in the Al x Ga 1Ϫx N epilayers with large Al content.

Friction is the basic, ubiquitous mechanical interaction between two surfaces that results in resistance to motion and energy dissipation. In spite of its technological and economic significance, our ability to control friction remains modest, and our understanding of the microscopic processes incomplete 1-3 . At the atomic scale, mismatch between the two contacting crystal lattices can lead to a reduction of stick-slip friction (structural lubricity) 4-7 , while thermally activated atomic motion can give rise to a complex velocity dependence 8-14 , and nearly vanishing friction at sufficiently low velocities (thermal lubricity) 10,13 . Atomic force microscopy has provided a wealth of experimental results 6-9,14-19 , but limitations in the dynamic range, time resolution, and control at the single-atom level have hampered a full quantitative description from first principles 3 . Here, using an ion-crystal friction emulator with single-atom, single substrate-site spatial resolution and single-slip temporal resolution 5,20 , we measure the friction force over nearly five orders of magnitude in velocity, and contiguously observe four distinct regimes, while controlling temperature and dissipation. We elucidate the interplay between thermal and structural lubricity in a system of two coupled atoms, and provide a simple explanation in terms of the Peierls-Nabarro potential 21 . This extensive control at the atomic scale paves the way for fundamental studies of the interaction of many-atom surfaces, as for example in the Frenkel-Kontorova model 21 , and possibly into the quantum regime 22 .

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Nanometer-sized columns of condensed water molecules are created by an atomic-resolution force microscope operated in ambient conditions. Unusual stepwise decrease of the force gradient associated with the thin water bridge in the tip-substrate gap is observed during its stretch, exhibiting regularity in step heights (≈ 0.5 N/m) and plateau lengths (≈ 1 nm). Such "quantized" elasticity is indicative of the atomic-scale stick-slip at the tip-water interface. A thermodynamic-instabilityinduced rupture of the water meniscus (5-nm long and 2.6-nm wide) is also found. This work opens a high-resolution study of the structure and the interface dynamics of a nanometric aqueous column.PACS numbers: 07.79. 07.79.Lh, 47.17.+e, 62.10.+s Water is one of the most important substances of life and has been studied extensively for hundreds of years. Nonetheless, it is still quite a unique matter that keeps surprising us and exhibits peculiarities, in particular, when confined in a nanometric configuration. For example, water and simple organic liquids exhibit solid-like orderedness in molecularly thin films [1,2,3]. Water molecules inside hydrophobic nanotubes manifest phases of ice that are not found under bulk conditions [4]. However, since bulk water possesses only short-range order [5] and water molecules move incessantly, it is usually difficult to experimentally investigate novel features of confined water structures other than thin films.In this Letter, we have employed an atomic-resolution noncontact atomic force microscope (AFM) in air [6] and achieved the spontaneous formation of a nanometric liquid column consisting of thousands of water molecules. We also have performed the sensitive measurement of the elastic property (or the force gradient) of the thin water column during its mechanical stretch. We have thereby demonstrated several novel phenomena: (i) the unusual stepwise decrease of the force gradient, associated with the atomic-scale stick-slip on the AFM-tip surface, (ii) the abrupt rupture of the thin water meniscus due to the thermodynamic instability of the liquid-vapor interface, and (iii) the manipulation of the thin aqueous column by repeated stretch-relaxation cycles, revealing the atomicscale contact angle hysteresis.Water molecules in ambient conditions produce a nanoscale water meniscus between a hydrophilic Si tip and a hydrophilic mica substrate, when capillary condensation occurs as the stiff AFM tip approaches the substrate within a nanometric distance (Fig. 1). Once the thin aqueous column is formed, it is stretched vertically upward by subsequent retraction of the tip. As the molecular water bridge of sub-zeptoliter (zepto = 10 −21 ) volume is elongated thereby, the force gradient associated with the elasticity of the system is measured by an ex- * Corresponding author: whjhe@snu.ac.kr tremely small amplitude-modulation operation of AFM [7,8]. Figure 1 presents the schematics of a home-built AFM setup used for formation of a nanometric water column by capillary condensation as well as for si...