Die Desoxygenierungsreaktionen der Thiocarbonate (I), (III) und (IV) (Synthesen aus bereits bekannten Dithioacetalen werde im experimentellen Teil beschrieben) nach A) werden untersucht.
1992 ring closure reactions ring closure reactions O 0130 46 -076 5-Carba Analogues of Sugars. Part 1. Radical Cyclization of Hept-1enitols.-7-Deoxy-7-iodohept-1-enitols, e.g. (I) (preparation given), are converted to 5-carbapyranose analogues upon treatment with tri-n-butylstannane in the presence of AIBN and subsequent deprotection. ( Mechanism, 12 examples). -(REDLICH, H.; SUDAU, W.; SZARDENINGS, A. K.; VOLLERTHUN, R.; Carbohydr. Res. 226 (1992) 1, 57-78; Org.-Chem. Inst.,
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