Tri(mesityloxy)silanethiol (TMST) was isolated as the only product of the reaction between SiS2 and 2,4,6‐trimethylphenol. TMST crystallizes in the triclinic system. Good quality of the crystal allowed the unrestricted refinement of the mercapto group; the resulting S–H distance is 1.29(4) Å and the Si–S–H bond angle is 95.4(17)°. Molecules of TMST show no hydrogen bonds in the crystal – the FT‐IR spectrum of the solid sample exhibits a very sharp, well‐resolved band of isolated –SH group at 2562 cm–1.
Abstract-This paper presents the investigations of nonreciprocal devices employing a novel ferrite coupled line junction. The structure is designed using coplanar line technology with the ground half-planes reduced to the strips. The investigated junction is composed of one ferrite section placed in between of two dielectric sections. In the ferrite section the longitudinally magnetized ferrite slab is located at the top or the bottom of the strips and is covered with the dielectric layers. In the dielectric sections the ports of the junctions are located. The wave parameters and field distributions of the modes propagated in the dielectric and ferrite sections are obtained from spectral domain approach. In order to determine the scattering matrix of the junction the mode matching method is utilized. The investigation of the circulator and isolator designed based on the Smatrix of the junction are presented. The obtained results are verified by comparing them with HFSS simulations and own measurements of the fabricated devices. In both cases a very good agreement is observed.
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