Observations have been made of the submillimetre wavelength radiation emitted by the lower stratosphere, using techniques of Fourier transform spectroscopy, while flying in a Comet 2E aircraft. Using the method of phase-modulation high quality spectra have been obtained at several altitudes over the spectral range 20 to 66 cm-I, and these have enabled identification of many emission lines due to O2 and Oj, in addition to those of H,O. Also several unidentified emission lines have been observed. The meteorological applications of this spectroscopic technique are considered. In particular, a direct method of comparing the emission of 'strong' water-vapour and oxygen lines enables a calculation of mixing ratio of water vapour in the stratosphere to be made, and a value of (2.1 f-0.3) x g/g is derived above an altitude of 12.2 km. A similar comparison for omne has given an integrated concentration of 0.35 & 0.10 cm atm in the vertical path above the observer. The merits of these observations in measuring stratospheric mixing ratios are discussed with respect to alternative techniques, in particular with reference to balloon-borne studies. ' Stratospheric humidity as determined from the absorption of solar radiation by a resolved spectral structure of water vapour I , Izu. Atm. Ocean. Phys., 4, pp. 826-834. ' Measurements of atmospheric infrared emission with a balloon-borne multifilter radiometer ', Quart. J. R. Met. ' Solid state devices for infrared detection ', J. Sci. Instruments, ' The width of the water vapour absorption line at A = 0-92 mm ', Sou. Radiophysics, 9, pp. 621-627. ' The far infrared spectrum of D,O ', Ph. D. thesis, Ohio State University. ' Theory of the fine structure of the molecular oxygen ground state ', Phys. Rev., 97, pp. 937-951. ' Line breadths in the microwave magnetic resonance spectrum of oxygen ', Ibid., 99, pp. 537-539. ' Fourier spectroscopy ', Prog. in Opt., 6, pp. 261-330. ' Radiometric measurements of emission from stratospheric water vapour I , Quart. J. R. Met. SOC., 91, pp, 330-338. ' Pure rotation spectrum of water vapour ', Report ERDA-2, Environmental Studies Dept., U. S. Army, White Sands, N. Mexico. ' Moisture contamination at altitude by balloon and associated equipment I , J. Geophys. Res., 71, pp. 3,775-3,778. SOC., 95, pp. 535-543. 43, pp. 857-868.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.
customersupport@researchsolutions.com
10624 S. Eastern Ave., Ste. A-614
Henderson, NV 89052, USA
Copyright © 2024 scite LLC. All rights reserved.
Made with 💙 for researchers
Part of the Research Solutions Family.