Understanding the wear characteristics of bone cement and its alternatives is critical to improving the quality and longevity of hip replacements. A novel composite material, self-reinforced composite poly(methyl methacrylate), has been previously developed for potential use as a pre-coat material for hip implants. The goal of this work was to examine the properties of self-reinforced composite poly(methyl methacrylate) as a function of processing temperature. Nanoindentation tests were performed to measure hardness and modulus of self-reinforced composite poly(methyl methacrylate) at the nanoscale. Nanoscratch tests were performed parallel, orthogonal, and longitudinal to composite fibers to measure residual scratch depths. Significant differences were found in the hardness, modulus, and residual scratch depth as a function of processing temperature when compared to poly(methyl methacrylate). As processing temperature is increased, hardness decreased and residual scratch depths increased. Data also showed that fiber orientation plays a critical role in scratch resistance. Scratching orthogonal to fiber orientation produced the least residual scratch depth ranging from 524 nm at 105 degrees C to 838 nm at 150 degrees C, compared to a residual scratch depth for poly(methyl methacrylate) of 842 nm.
Femoral components of hip replacements are commonly anchored in the femur with bone cement or poly(methyl methacrylate) (PMMA). Wear or fracture of bone cement can lead to loosening of the femoral component, which drastically affects the success and longevity of hip replacements. Self-reinforced composite PMMA (SRC-PMMA) has been previously developed for potential use, as a precoat material for hip replacements. The composite consists of high strength fibers that have been shown to have greatly improved mechanical properties over bulk PMMA. The goal of this work was to examine SRC-PMMA for improved wear properties, as a function of processing temperature. Pin-on-disc tests were used to characterize and rank the wear rates of SRC-PMMA and PMMA. Composites made with higher processing temperatures had significantly lower wear rates than do PMMA at a significance level of p < or = 0.05. The lowest wear rate was 8.2 microg/m, at a processing temperature of 136 degrees C, compared to a wear rate for PMMA of 13.3 microg/m. At the lowest processing temperature (105 degrees C), a wear rate higher than PMMA was found, and failure was dominated by fiber delamination. In the more completely processed samples (122 degrees C < or = T < or = 150 degrees C), wear rates were equivalent to or better than PMMA, and smoother and more homogenous wear was noted in wear tracks. Fatigue cracks were prominent at higher processing temperatures or when the wear pin was riding orthogonal to fibers. Wear particles were collected and examined. Wear particle diameter and aspect ratio showed no correlation to processing temperature, but were similar to particles retrieved from human tissue samples.
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