Organic chemists have been able to develop a robust, theoretical understanding of the phenomena they study; however, the primary theoretical devices employed in this field are not mathematical equations or laws, as is the case in most other physical sciences. Instead it is diagrams, and in particular structural formulas and potential energy diagrams, that carry the explanatory weight in the discipline. To understand how this is so, it is necessary to investigate both the nature of the diagrams employed in organic chemistry and how these diagrams are used in the explanations of the discipline. I will begin this paper by characterizing some of the major ways that structural formulas used in organic chemistry. Next I will present a model of the explanations in organic chemistry and describe how both structural formulas and potential energy diagrams contribute to these explanations. This will be followed by several examples that support my abstract account of the role of diagrams in the explanations of organic chemistry. In particular, I will consider both the appeal to 'hyperconjugation' in the explanation of alkene stability and how the idea of 'ring strain' was developed to explain the relative stability of cyclic compounds.
In this paper, a model of a subclass of the explanations given in organic chemistry is developed. This model is supported by three concrete examples. The model suggests that in this discipline, laws, theories, and causal reasoning are interrelated in interesting and heretofore unexplored ways. The model also reserves a prominent place for idealizations and capacities ascribed on the basis of the structural features of molecules. The author hopes to have established that philosophical reflection on the methodology of organic chemistry can yield interesting and valuable new insights into classical issues in the philosophy of science.
This paper considers two recent arguments that structure should not be regarded as the fundamental individuating property of proteins. By clarifying both what it might mean for certain properties to play a fundamental role in a classification scheme and the extent to which structure plays such a role in protein classification, I argue that both arguments are unsound. Because of its robustness, its importance in laboratory practice, and its explanatory centrality, primary structure should be regarded as the fundamental distinguishing characteristic of protein taxonomy.
This paper characterizes the increase in ‘scientific understanding’ that resulted from the Ingold Revolution in organic chemistry. By describing both the sorts of explanations facilitated by Ingold's Revolution and the sense in which organic chemistry was ‘unified’ by adopting these approaches to explanation, one can appreciate how this revolution led to a dramatic qualitative improvement in organic chemists’ understanding of the phenomena that they study. The explanatory unification responsible for this transformation in organic chemistry is contrasted with contemporary philosophical accounts of unification and its relationship to both scientific understanding and explanation.
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