A method is presented for deriving a volume model of groundwater total dissolved solids (TDS) from borehole geophysical and aqueous geochemical measurements. While previous TDS mapping techniques have proved useful in the hydrogeologic setting in which they were developed, they may yield poor results in settings with lithological heterogeneity, complex water chemistry, or limited data. Problems arise because of assumed values for empirical constants in Archie's Equation, unrealistic porosity and temperature gradients, or bicarbonate-rich groundwater. These issues become critical in complex geologic settings such as the San Joaquin Valley of California, USA. To address this, a method to map TDS in three dimensions is applied to the Fruitvale and Rosedale Ranch oil fields near Bakersfield, California. Borehole resistivity, porosity, and temperature data are used to derive TDS using Archie's Equation, and are then kriged to interpolate TDS. Archie's a and m (tortuosity factor and cementation exponent, respectively) are found by comparing model predictions, after kriging, to TDS measurements, and minimizing the differences via mathematical optimization. Contributions of abundant bicarbonate ions to TDS were corrected using an empirical model. This work was motivated by federal and state law requirements to monitor and protect underground sources of drinking water. Modeling shows the legally significant boundary of 10,000 ppm TDS is at~1,067 m below sea level in Rosedale Ranch, and deepens into Fruitvale to~1,341 m. Mapping groundwater TDS at this resolution reveals that TDS is primarily controlled by depth, recharge, stratigraphy, and in some places, by faulting and facies changes.
Groundwater total dissolved solids (TDS) distribution was mapped with a three-dimensional (3D) model, and it was found that TDS variability is largely controlled by stratigraphy and geologic structure. General TDS patterns in the San Joaquin Valley of California (USA) are attributed to predominantly connate water composition and large-scale recharge from the adjacent Sierra Nevada. However, in smaller areas, stratigraphy and faulting play an important role in controlling TDS. Here, the relationship of stratigraphy and structure to TDS concentration was examined at Poso Creek Oil Field, Kern County, California. The TDS model was constructed using produced water TDS samples and borehole geophysics. The model was used to predict TDS concentration at discrete locations in 3D space and used a Gaussian process to interpolate TDS over a volume. In the overlying aquifer, TDS is typically <1,000 mg/L and increases with depth to ~1,200–3,500 mg/L in the hydrocarbon zone below the Macoma claystone—a regionally extensive, fine-grained unit—and reaches ~7,000 mg/L in isolated places. The Macoma claystone creates a vertical TDS gradient in the west where it is thickest, but control decreases to the east where it pinches out and allows freshwater recharge. Previously mapped normal faults were found to exhibit inconsistent control on TDS. In one case, high-density faulting appears to prevent recharge from flushing higher-TDS connate water. Elsewhere, the high-throw segments of a normal fault exhibit variable behavior, in places blocking lower-TDS recharge and in other cases allowing flushing. Importantly, faults apparently have differential control on oil and groundwater.
The effects of oil and gas production on adjacent groundwater quality are becoming a concern in many areas of the United States. As a result, it has become increasingly important to identify which aquifers require monitoring and protection. In this study, we map the extent of groundwater with less than 10,000 mg/L TDS both laterally and vertically near the Elk Hills, Buena Vista and Coles Levee Oil Fields in the San Joaquin Valley, California and note evidence of effects of produced water disposal on salinity within the Tulare aquifer. Subsurface maps showing the depth at which groundwater salinity is less than 10,000 mg/L (or Base 10K) in the Tulare aquifer are generated using geophysical logs and verified by comparison to water sample analyses. The depth to Base 10K ranges from 240 m (800 ft) in Elk Hills to 800 m (2650 ft) in the adjacent Buena Vista syncline and is 670 m (2,200 ft) deep in the Coles Levee area to the east. Log-calculated salinities show a relatively smooth increase with depth prior to disposal activities whereas salinities calculated from logs collected near and after disposal activities show a more variable salinity profile with depth. The effect of produced water injection is represented by log resistivity profiles that change from low resistivity at the base of the sand to higher resistivity near the top due to density differences between the saline produced water and the brackish groundwater within each sand. Continued post-disposal logging in new wells in the 18G disposal area on the south flank of Elk Hills shows that injected water has migrated approximately 1,200 m (4,000 ft) downdip (south) over a period of 20 years since the inception of disposal activity.
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