The battery powder (anodic and cathodic mass) manually separated from spent Li-ion batteries used in laptops was subjected to acidic reductive leaching to recover the Co, Li, and Ni contained in it. In the laboratory experiments, 1.5 M sulfuric acid was used as the leaching agent and the reducing agents were 30% H2O2 solution or/and glutaric acid. Glutaric acid is a potential new reducing agent in the leaching process of spent lithium-ion batteries (LIBs). The influence of the type of the used reducer on obtained recovery degrees of Co, Li, and Ni as well as the synergism of the two tested reducing compounds were analyzed. As a result, it was determined that it is possible to efficiently hydrometallurgically separate Co, Li, and Ni from battery powder into solutions. The highest recovery degrees of the investigated metals (Co: 87.85%; Li: 99.91%; Ni: 91.46%) were obtained for samples where two reducers, perhydrol and glutaric acid, were added, thus confirming the assumed synergic action of H2O2 and C5H8O4 in a given reaction environment.
The automotive industry is one of the fastest-growing sectors of the modern economy. Growing customer expectations, implementing solutions related to electromobility, and increasingly stringent legal restrictions in the field of environmental protection, determine the development and introduction of innovative technologies in the field of car production. To power the most modern vehicles that include electric and hybrid cars, packages of various types of lithium-ion cells are used, the number of which is constantly growing. After use, these batteries, due to their complex chemical composition, constitute hazardous waste that is difficult to manage and must be recycled in modern technological lines. The article presents the morphological characteristics of the currently used types of Li-ion cells, and the threats to the safety of people and the environment that may occur in the event of improper use of Li-ion batteries and accumulators have been identified and described on the basis of the Regulation of the European Parliament and Council (EC) No. 1272/2008 of 16 December 2008 and No. 1907/2006 of 18 December 2006 on the classification, labeling and packaging of substances and mixtures and the registration, evaluation, authorization and restriction of chemicals (REACH), establishing the European Chemicals Agency.
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